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Diss Factsheets
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EC number: 639-469-7 | CAS number: 14907-27-8
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
Pay attention to self-protection.
Remove victims from hazardous area.
Immediately remove soiled or soaked clothing and remove it to a safe distance.
Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
In case of inhalation:
Inhalation is possible if aerosols, mists, dusts, or smoke form.
Move victims into fresh air.
If the causality is no breathing perform mouth to mouth resuscitation, notify emergency physician immediately.
Skin contact:
Wash off immediately affected area immediately with plenty of water for at least 15 minutes.
If symptoms persist: consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
In case of discomfort: consult an ophthalmologist.
Ingestion:
Rinse out mouth.
Consult a physician immediately.
Most important symptoms and effects, both acute and delayed:
The initial focus is only on the local action, characterized by quickly progressing deep tissue damage.
Coughing is a symptom of respiratory tract after inhalation of dusts or smoke from caustic solids.
In the eye, caustic dusts or smoke cause, depending on the intensity of exposure, severe irritation, destruction, and ablation of the epithelium of the conjunctiva and cornea, corneal clouding, edema and ulcerations.
Danger! Possible loss of eyesight!
Superficial irritations and damage up to ulcerations and scarring develop on the skin.
Fire-fighting measures
Extinguishing media:
All extinguishing substances suitable.
Water, spray water, CO2, extinguishing powder, specific foam.
Special hazards arising from the substance or mixture:
In the case of fire, the following hazardous smoke fumes may be produced:
Carbon monoxide, carbon dioxide - nitrogen oxides (NOx) – hydrogen chloride (HCl)
Advice for firefighters:
Wear personal protective equipment.
In the event of fire, wear self-contained breathing apparatus.
Fire residues should be disposed in accordance with the regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Wear personal protective equipment.
Keep unauthorized persons away.
Environmental precautions:
Do not allow the product into the following compartments: soil, stretches of water, drainage systems.
In case of pollution, inform competent authorities.
Methods and material for containment and cleaning up:
Pick up mechanically.
Collect in suitable containers.
Waste to be packed like clean product and to be labelled.
Identification label on packages not to be removed until recycling.
Observe regulation on prevention of water pollution (check, dam up, cover up).
Handling and storage
Precautions for self handling:
Handle and transfer products in closed systems only (gas displacement device).
Ensure that apparatus and pipelines are free from leaks.
Dedicated loading/unloading stations are required.
Avoid residues of products on the containers.
Take precautionary measures against static discharges.
Ensure suitable suction/aeration at the work place and with operational machinery (gas scrubber for example).
Keep away from sources of ignition – No smoking.
Further information: VDI 2263 "Dust fires and dust explosions; dangers, evaluation, preventive measures.”
Conditions for safe storage, including any incompatibilities:
Keep containers in a dry and dark place in its original packaging, tightly closed.
Label according to the regulations.
Specific end of use(s):
Follow usual safety precautions while handling.
Transport information
Land transport (UN RTDG/ADR/RID)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as dangerous in the meaning of transport regulations.
Inland waterway transport (UN RTDG/ADN(R))
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Special provisions / remarks
- Remarks:
- Not classified as dangerous in the meaning of transport regulations.
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as dangerous in the meaning of transport regulations.
Air transport (UN RTDG/ICAO/IATA)
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Special provisions / remarks
- Remarks:
- Not classified as dangerous in the meaning of transport regulations.
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters:
Remarks: No substance-specific value being known.
Exposure controls:
The substance must be handled under strictly controlled conditions.
Personal protective equipment:
Respiratory protection equipment:
If dust occurs: dust mask with P2 particle filter size.
Note time limit for wearing respiratory protective equipment.
Hand protection:
Wear gloves
Brief contact only:
Glove material: rubber, Nitril for example, material thickness: minimum 0.11 mm
Accidental release measures:
Glove material: Nitril/Chloroprene for example, material thickness: minimum 0.65 mm
Eye protection:
Safety glasses with side-shields conforming to EN166.
Accidental release measures or when handling larger quantities: basket-shaped glasses".
Skin and body protection:
Light weight protective clothing.
Skin and body protection:
Use lab protective clothing.
Accidental release measures:
Cloth specific for chemical products.
Hygiene measures:
Avoid contact with skin and eyes.
No eating, drinking, smoking or snuffing tobacco at work.
Wash face and/or hands before break and end of work.
Protective measures:
Handle in accordance with good industrial hygiene and safety practices.
It should be defined in the work place in the form of a risk analysis.
All precautions must be strictly observed.
Regular safety training is a must.
Stability and reactivity
Reactivity:
No dangerous reactivity known.
Chemical stability:
Easily hydrolysable in contact with water.
Possibility of hazardous reactions:
No dangerous reaction are known to occur with correct handling and storage.
Conditions to avoid:
Avoid moisture , sunrays, heat.
On grinding inertisation is necessary.
Incompatible materials:
Slight potential risk of chloride corrosion is suspected with metal materials.
Hazardous decompositions products:
Carbon monoxide, carbon dioxide, nitrogen oxides (NOx), hydrogen chloride (HCl).
Disposal considerations
Waste treatment methods:
Disposal according to local authority regulations.
Waste to be packed like clean product and to be labelled.
Identification label on package not to be removed until recycling.
Waste Key Number:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.