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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Ecotoxicological information

Ecotoxicological Summary

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Administrative data

Hazard for aquatic organisms

Freshwater

Hazard assessment conclusion:
PNEC aqua (freshwater)
PNEC value:
0.2 mg/L
Assessment factor:
10
Extrapolation method:
assessment factor
PNEC freshwater (intermittent releases):
0.56 mg/L

Marine water

Hazard assessment conclusion:
PNEC aqua (marine water)
PNEC value:
0.02 mg/L
Assessment factor:
100
Extrapolation method:
assessment factor
PNEC marine water (intermittent releases):
0.56 mg/L

STP

Hazard assessment conclusion:
no hazard identified

Sediment (freshwater)

Hazard assessment conclusion:
PNEC sediment (freshwater)
PNEC value:
1.05 mg/kg sediment dw
Extrapolation method:
equilibrium partitioning method

Sediment (marine water)

Hazard assessment conclusion:
PNEC sediment (marine water)
PNEC value:
0.105 mg/kg sediment dw
Extrapolation method:
equilibrium partitioning method

Hazard for air

Air

Hazard assessment conclusion:
no hazard identified

Hazard for terrestrial organisms

Soil

Hazard assessment conclusion:
PNEC soil
PNEC value:
0.093 mg/kg soil dw
Extrapolation method:
equilibrium partitioning method

Hazard for predators

Secondary poisoning

Hazard assessment conclusion:
no potential for bioaccumulation

Additional information

Conclusion on classification

Classification related key information

Biodegradation in water: 84% (BOD)

BCF: 255 L/kg in fish after 28 days exposure (OECD 305); read across

 

Acute toxicity:

- to fish: LC50 (96 h) = 88 mg/L for Pimephales promelas (nominal, similar to OECD 203)

- to invertebrates: EC50 (48 h) = 72 mg/L for Daphnia m.(nominal, OECD 202); read across

- to algae: ErC50 (72 h) = 56.4 mg/L for Selenastrum c.(nominal, OECD 201); read across

 

Chronic toxicity:

- to fish: NOEC (28 d) = 2.0 mg/L for Danio r. (nominal, OECD 305 E); read across

- to invertebrates: NOEC (21 d) = 17.9 mg/L for Daphnia m.(TWA, OECD 211); read across

- to algae: NOErC (72 h) = 32 mg/L for Selenastrum c.(nominal, OECD 201); read across

 

Classification justification according to CLP

Hexanoic acid (CAS 142-62-1) is considered to be rapidly degradable. The acute aquatic toxicity L(E)C50 values are > 1 mg/L for fish, invertebrates and algae. Valid read-across chronic toxicity data are available - the NOECs are > 1 mg/L for fish, invertebrates and algae. Therefore, hexanoic acid (CAS 142-62-1) does not need to be classified and labelled as environmental hazard according to the consolidated version of Regulation (EC) No 1272/2008 and further amendments (ATPs).