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Physical & Chemical properties

Oxidising properties

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Description of key information

This product  no has oxidizing properties. Aluminim sulphate is from the group of Inorganic salt and do not contain an organic materials and the substance is incapable of reacting exothermically with combustible materials, on the basis of the chemical structure.
Aluminim sulphate is an inorganic substance with a relatively large number of oxygen atoms per molecule but no hydrogen or carbon atoms. There are no structural alerts with regard to oxidising potential of the substance.
The substance does not contain groups that act as an oxidizing agent. The oxygen atoms that are present in the molecular structure of the test substance are chemically bonded to sulfur or hydrogen.
EU Test method A17 for determination of oxidising properties states that the test need not be performed when examination of the structural formula established beyond reasonable doubt that the substance is in capable of reacting exothermically with a combustible material.

Key value for chemical safety assessment

Oxidising properties:
no

Additional information

Oxidising properties

Aluminim sulphate belongs to the Following Reactive Group: Salts, Acidic Inorganic/Organic. There are 271 chemical datasheets assigned to this reactive group.

Reactive groups are categories of chemicals that typically react in similar ways because they are similar in their chemical structure. Each substance with a chemical datasheet has been assigned to one or more reactive groups, and CAMEO Chemicals uses the reactive group assignments to make its reactivity predictions.

Aluminim sulphate is an inorganic substance with a relatively large number of oxygen atoms per molecule but no hydrogen or carbon atoms. There are no structural alerts with regard to oxidising potential of the substance.

The substance does not contain groups that act as an oxidizing agent. The oxygen atoms that are present in the molecular structure of the test substance are chemically bonded to sulfur or hydrogen.

EU Test method A17 for determination of oxidising properties states that the test need not be performed when examination of the structural formula established beyond reasonable doubt that the substance is in capable of reacting exothermically with a combustible material. 

Aluminim sulphate is from the group of Inorganic salt and do not contain an organic materials and the substance is incapable of reacting exothermically with combustible materials, on the basis of the chemical structure.

 

Aluminim sulphate has not oxidizing properties.(Daubert, T.E. and Danner, R.P. Physical and Thermodynamic Properties of Pure Chemicals Data Compilation. Washington, Taylor Francis, 1989)

Justification for classification or non-classification

Based on the hazard assessmentof aluminium sulphate in section 2.1 and 2.2in IUCLID 5.4, availabledata for the substance and according to the criteria described in Directive 67/548/EEC and in the Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures (CLP Regulation):

 

Directive 67/548

E;R2 Risk of explosion by shock, friction, fire or other sources of ignition

E;R3 Extreme risk of explosion by shock, friction, fire or other source of ignition

O; R7 May cause fire

O; R8 Contact with combustible material may cause fire

O; R9 Explosive when mixed with combustible material

F+; R12 Extremely flammable

F; R11 Highly flammable

F; R15 Contact with water liberates extremely flammable gas

F; R17 Spontaneously flammable in air

R10 Flammable

 

CLP Regulation

H242 Org. Perox. CD Heating may cause a fire

H242 Org. Perox. EF Heating may cause a fire

Gas: H270 Ox. Gas 1: May cause or intensify fire; oxidiser

Liquid: H271 Ox. Liq 1 May cause fire or explosion; strong oxidiser

Solid: H271 Ox. Sol 1 May cause fire or explosion; strong oxidiser

H272: May intensify fire; oxidiser

Gas: H220 Flam. Gas 1: extremely flammable gas

Gas: H221 Flam. Gas 2: flammable gas

Aerosol: H222 Category 1: extremely flammable aerosol

Aerosol:H223 category 2: flammable aerosol

Liquid: H224 Flam. Liq. 1

H242 Self-react. CD: Heating may cause a fire

H242 Self-react. EF: Heating may cause a fire

None Self-react. G

Liquid: H224 Flam. Liq. 1, if initial boiling point <35ºC

Liquid: H225 Flam. Liq. 2, if initial boiling point >35ºC

Solid: H228: Flammable solid

Solid: H250, Pyr. Liq. 1: Catches fire spontaneously if exposed to air

Liquid: H250, Pyr. Sol. 1: Catches fire spontaneously if exposed to air

Liquid: H224 Flam. Liq. 1, if flashpoint<23ºC and initial boiling point<35ºC

Liquid: H225 Flam. Liq. 2, if flashpoint<23ºC and initial boiling point>35ºC

Liquid: H226 Flam. Liq. 3, if flashpoint>23ºC

H200: unstable explosive

H201: explosive; mass explosion hazard

H202: explosive; severe projection hazard

H203: explosive; fire, blast or projection hazard

H204: Fire or projection hazard

H205: may mass explode in fire

H280: contains gas under pressure; may explode if heated

H281: contains refrigerated gas; may cause cryogenic burns or injury

H240: heating may cause an explosion

H241: Heating may cause a fire or explosion

H251: Self-heating; may catch fire

H252: Self-heating in large quantities; may catch fire

H260: In contact with water releases flammable gases which may ignitespontaneously

H261: In contact with water releases flammable gases

H290: May be corrosive to metals

It is concluded that none of the above phrase has not to be assigned to aluminium sulphate and   does not meet the criteria to be classified for oxidizing properties.