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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
oxidising solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2012
Reliability:
1 (reliable without restriction)
Qualifier:
according to guideline
Guideline:
EU Method A.17 (Oxidising Properties (Solids))
Deviations:
not applicable
Remarks:
Preliminary determination only
GLP compliance:
yes (incl. QA statement)
Contact with:
powdered cellulose
Sample tested:
other: not specified
Parameter:
other: not specified
Remarks on result:
other: result not specified (migrated information) TBS did not burn, but evaporated out of the cellu lose to leave a charred solid
Sample tested:
test mixture (not specified)
Parameter:
maximum burning rate
Result:
97 s

The molecular structure of TBS does not contain any oxidising groups such as peroxide, chlorate, perchlorate, nitrate, bromate, chromate, etc. Therefore, in our considered opinion, there is no realistic possibility that the formulation presents an Oxidation hazard. In order to reinforce the above statement, oxidising property determinations were carried out according to the preliminary determination given in EEC A17.

TBS did not burn, but evaporated out of the cellulose to leave a charred solid

The efficacy of the method was tested, as described in the method, using a 60:40 reference mix of Barium Nitrate: Cellulose. A cone was prepared, as above, and placed on the platinum wire. The standard specimen exhibited a vigorous reaction with a steady fame. Reaction completed in approximately 1 minute 37 seconds.

Interpretation of results:
GHS criteria not met
Conclusions:
TBS is non-flammable and lacking oxidising groups in the molecule, there is no realistic possibility that TBS presents an Oxidation hazard.
Executive summary:

The oxidising properties of TBS were assessed as described in EEC A17. TBS did not burn but evaporated out of the cellulose. TBS is non-flammable and lacking oxidising groups in the molecule,there is no realistic possibility that TBS presents an Oxidation hazard.

Description of key information

The substance does not contain any oxidising groups and, although it is flammable, does not present an oxidation hazard.

Key value for chemical safety assessment

Oxidising properties:
non oxidising

Additional information

Justification for classification or non-classification

No oxidising groups present and does not meet the criteria when tested according to EEC A17.