Reaction product of {mixture of [poly(1~4)chlorosulfonylphthalocyaninato-N29,N30,N31,N32]copper(Ⅱ) and [poly(1~3) chlorosulfonyl (tribenzo[b,g,l]pyrido[2,3-q]-5,10,15,20-tetraazaporphyrinato-N21,N22,N23,N24)] copper(Ⅱ) and [poly(1~2) chlorosulfonyl (dibenzo[b,g(or b,l)]dipyrido [2,3(or 3,2)-l,q(or g,q)]-5,10,15,20-tetraazaporphyrinato-N21,N22,N23,N24)] copper(Ⅱ) and [monochlorosulfonyl (benzo[b]tripyrido [2,3(or 3,2)-g,l,q]-5,10,15,20-tetraazaporphyrinato-N21,N22,N23,N24)]copper(Ⅱ) }and 2-[4-(2-aminoethylamino)-6-(benzylamino)-1,3,5-triazin-2-ylamino]benzene-1,4-disulfonic acid, and ammonia water and sodium chloride

Explosiveness

Administrative data

Endpoint:

explosive properties of explosives

Type of information:

experimental study

Adequacy of study:

key study

Study period:

11 February 2011 – 27 April 2011

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

other: This study has been performed according to UN and EC guidelines and in compliance with GLP principles.

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

2011

Report date:

2011

Materials and methods

Test guideline

Test guideline 1

Qualifier:

according to guideline

Guideline:

other: United Nations (UN), UN no. ST/SG/AC.10/11/Rev.4: RTDG, Part I; Section 13: “Test Series 3”, 2003.

Deviations:

no

Test guideline 2

Qualifier:

according to guideline

Guideline:

other: United Nations (UN), UN no. ST/SG/AC.10/11/Rev.4: RTDG, Appendix 6: “Screening Procedures”, 2003.

Deviations:

no

Test guideline 3

Qualifier:

according to guideline

Guideline:

EU Method A.14 (Explosive properties)

Version / remarks:

(Official Journal of the European Union no. L142, May 31, 2008)

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Test material

Test material information

Constituent 1

Reference substance name:

E-C104

IUPAC Name:

E-C104

Details on test material:

- Name of test material (as cited in study report): E-C104
- Description: Blue powder
- Batch: MB-1
- Test substance storage: At room temperature protected from light
- Stability under storage conditions: Stable
- Expiry date: 23 December 2015

Results and discussion

Small-scale preliminary tests

Small-scale preliminary tests 1

Parameter:

other: More sensitive to shock than m-dinitrobenzene

Remarks:

migrated information

Remarks on result:

not measured/tested

Small-scale preliminary tests 2

Parameter:

other: More sensitive to friction than m-dinitrobenzene

Remarks:

migrated information

Remarks on result:

not measured/tested

Small-scale preliminary tests 3

Parameter:

other: Explosive under influence of flame

Remarks:

migrated information

Remarks on result:

not measured/tested

Small-scale preliminary tests 4

Parameter:

other: Explosive (not specified)

Remarks:

migrated information

Remarks on result:

negative (not further specified)

Remarks:

based on screening procedure as described in Regulation (EC) No 1272/2008, part 2, section 2.1.4.3 (c)

Any other information on results incl. tables

In the two experiments performed, a small endothermic peak between 100°C and 225°C was observed. It was most likely obtained due to evaporation of minor compounds in the test substance.

In both experiments, an exothermic decomposition effect starting at 225°C was observed. The extrapolated onset temperature of the effect in the first experiment was 364.99°C. In the second experiment an onset temperature 367.27°C was obtained. The exothermic decomposition energy was 174.3 J/g in the first experiment and 171.4 J/g in the second test.

Applicant's summary and conclusion

Interpretation of results:

GHS criteria not met

Conclusions:

The explosive properties of E-C104 were evaluated using DSC. Exothermic decomposition of the test substance was observed at a temperature of 386°C. The exothermic decomposition energy was 173 J/g. According to this it was considered that the test substance has no explosive properties.