Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
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Inhalation
Remove from exposure to fresh air. Seek medical advice.

Skin contact
Wash of immediately with soap and plenty of water removing all contaminated clothes and shoes.

Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical advice.

Ingestion
If swallowed seek medical advice immediately and show this safety data sheet to the doctor in attendance.

Most important symptoms and effects, both acute and delayed
May cause damage to organs through prolonged or repeated exposure if swallowed. Harmful if inhaled.

Indication of immediate medical attention and special treatment needed
Treatment according to symptoms.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media
foam, carbon dioxide (CO2), dry powders.

Extinguishing media which must not be used for safety reasons
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Special hazards arising from the substance or mixture
By heating or in fire toxic gases are liberating carbon and nitrogen oxides and hydrofluoric acid (HF).

Advice for firefighters
Standard procedure for chemical fires. Wear self-contained breathing apparatus and protective suit.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Wear suitable protective clothing, gloves and eye/face protection.

Environmental precautions
Prevent product entering drains. Should not be released into the environment. If water is used in fire extinguishing, prevent from entering drains or the environment

Methods and materials for containment and cleaning up
Sweep up and shovel into suitable containers for disposal. Keep container tightly closed. Avoid dust formation.

Reference to other sections
Information regarding personal protective equipmentm see section Exposure controls/Personal protection. Information regarding waste disposal, see section Disposal considerations.

Handling and storage

This substance is handled under Strictly controlled conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the strictly controlled conditions as specified in REACH regulation Article 18 (4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at the Manufacturing site.

Precautions for safe handling
Provide sufficient air exchange and/or exhaust in work rooms. Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed. When using do not eat or drink. When using do not smoke. Wear personal protective equipment.

Conditions for safe storage, including any incompatibilities
Keep container tightly closed. Keep out of reach of children. Keep away from food, drink and animal feeding stuffs. Keep away from strong oxidizing agents and strong bases.

Specific end use(s)
Not known.

Transport information

Land transport (ADR/RID)

UN number:
3077
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Class:
9
Classification code:
Risk code: 9
Packaging group:
III
Labels:
9
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Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
UN 3077 Environmentally hazardous substance, solid, n.o.s. (contains: 1-cyclopropyl 3-(2-methylthio 4-trifluoromethyl phenyl)1,3-propanedione)
Chemical name:
1-cyclopropyl 3-(2-methylthio 4-trifluoromethyl phenyl)1,3-propanedione
Class:
9
Packaging group:
III
Labels:
9
Marine pollutant
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Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
UN 3077 Environmentally hazardous substance, solid, n.o.s. (contains: 1-cyclopropyl 3-(2-methylthio 4-trifluoromethyl phenyl)1,3-propanedione)
Chemical name:
1-cyclopropyl 3-(2-methylthio 4-trifluoromethyl phenyl)1,3-propanedione
Class:
Risk code 9
Packaging group:
III
Labels:
9
Remarksopen allclose all
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Exposure controls / personal protection

This substance is handled under Strictly controlled conditions in accordance with REACH regulation Article 17 (3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the strictly controlled conditions as specified in REACH regulation Article 18 (4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site.

Control parameters
No specific treshold limits for this substance available.

Other information on limit values
Chlorobenzene:
HTP (8h) = 5 ppm = 23 mg/m3 (skin, Finland)
HTP (15 min) = 15 ppm = 70 mg/m3 (skin, Finland)
Odour treshold: Appr. 0.2 ppm

imit values on other countries
No data available.

DNELs
No data available.

PNECs
No data available.

Exposure controls

Appropriate engineering controls
Avoid contact with skin, eyes and clothing.

Individual protection measures

Respiratory protection
In case of sufficient ventilation wear suitable respiratory equipment (dust mask, P2).

Hand protection
Chemical resistant gloves (butyl, PVA).

Eye/face protection
Goggles.

Skin protection
Wear suitable protective clothing.

Environmental exposure controls
Should not be released into the environment.

Stability and reactivity

Reactivity
No specific reactivity to be expected when used and storage under normal recommended conditions.

Chemical stability
No data available.

Possibility of hazardous reactions
Not if used and storage under normal recommended conditions.

Conditions to avoid
Stable under normal conditions and use.

Incompatible materials
None under normal use.

Hazardous decomposition products
In the event of fire hazardous gases may be formed, carbon oxides, nitrogen oxides, HF-gas.

Disposal considerations

Dispose of as special waste in compliance with local and national regulations.

Waste treatment methods
Dispose of as special waste in compliance with local and national regulations.

Waste from residues/unused products
Dispose of as special waste in compliance with local and national regulations.