Registration Dossier
Registration Dossier
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EC number: 606-373-1 | CAS number: 197706-50-6
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
If inhaled:
If breathed in, move person into fresh air. If symptoms persist, call a physician.
In case of skin contact:
Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water.
Call a physician immediately. Wash contaminated clothing before reuse
In case of eye contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses. Consult a physician
If swallowed:
If swallowed, rinse mouth with water (only if the person is conscious). Call a physician immediately.
Most important symptoms and effects, both acute and delayed: May cause sensitisation by skin contact. Irritating to eyes. Irritating to skin.
Indication of any immediate medical attention and special treatment needed: treat symptpmatically
If breathed in, move person into fresh air. If symptoms persist, call a physician.
In case of skin contact:
Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water.
Call a physician immediately. Wash contaminated clothing before reuse
In case of eye contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses. Consult a physician
If swallowed:
If swallowed, rinse mouth with water (only if the person is conscious). Call a physician immediately.
Most important symptoms and effects, both acute and delayed: May cause sensitisation by skin contact. Irritating to eyes. Irritating to skin.
Indication of any immediate medical attention and special treatment needed: treat symptpmatically
Fire-fighting measures
Suitable extinguishing media:
Water mist
Dry powder
Foam
Carbon dioxide (CO2)
Sand
Aqueous film forming foam (AFFF).
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media: Water spray jet
Special hazards arising from the substance or mixture: Carbon oxides Fluorine compounds
Advice for firefighters:
Special protective equipment for firefighters:In the event of fire, wear self-contained breathing apparatus.
Specific extinguishing methods : In the event of fire, cool tanks with water spray.
Water mist
Dry powder
Foam
Carbon dioxide (CO2)
Sand
Aqueous film forming foam (AFFF).
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media: Water spray jet
Special hazards arising from the substance or mixture: Carbon oxides Fluorine compounds
Advice for firefighters:
Special protective equipment for firefighters:In the event of fire, wear self-contained breathing apparatus.
Specific extinguishing methods : In the event of fire, cool tanks with water spray.
Accidental release measures
Personal precautions:
Evacuate personnel to safe areas.
Ensure adequate ventilation.
Keep away from open flames, hot surfaces and sources of ignition.
Environmental precautions:
Should not be released into the environment.
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up :
Large spills: Dam up. Soak up with inert absorbent material. Keep in properly labelled containers.
Small spills: Gently cover the spill with an absorbent towel or pad.
Large spills + Small spills: Keep in suitable, closed containers for disposal. Treat recovered material as described in the section "Disposal considerations".
Evacuate personnel to safe areas.
Ensure adequate ventilation.
Keep away from open flames, hot surfaces and sources of ignition.
Environmental precautions:
Should not be released into the environment.
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up :
Large spills: Dam up. Soak up with inert absorbent material. Keep in properly labelled containers.
Small spills: Gently cover the spill with an absorbent towel or pad.
Large spills + Small spills: Keep in suitable, closed containers for disposal. Treat recovered material as described in the section "Disposal considerations".
Handling and storage
Advice on safe handling:
To avoid thermal decomposition, do not overheat.
Use personal protective equipment as required.
Avoid inhalation, ingestion and contact with skin and eyes.
Advice on protection against fire and explosion: No data available
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice.
Requirements for storage areas and containers : To maintain product quality, do not store in heat or direct sunlight. Store in original container. Keep container tightly closed in a dry and well-ventilated place. Store at room temperature.
Recommended Storage temperature: 15 - 35 °C
Specific use(s): Consult the technical guidelines for the use of this substance/mixture.
To avoid thermal decomposition, do not overheat.
Use personal protective equipment as required.
Avoid inhalation, ingestion and contact with skin and eyes.
Advice on protection against fire and explosion: No data available
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice.
Requirements for storage areas and containers : To maintain product quality, do not store in heat or direct sunlight. Store in original container. Keep container tightly closed in a dry and well-ventilated place. Store at room temperature.
Recommended Storage temperature: 15 - 35 °C
Specific use(s): Consult the technical guidelines for the use of this substance/mixture.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ((-)-[R-(R*,R*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1-benzopyran)
- Labels:
- 9
Special provisions / remarks
- Special provisions:
- Special Provision 375: Environmentally Hazardous Substances/Marine Pollutants, classified under UN 3077 or UN 3082, packaged in single or combination packagings containing a net quantity per single of inner packaging of 5L or less for liquids or having a net mass per single of inner packaging of 5kg or less for solids are not subject to the ADR/RID/ADN/IMDG/IATA DGR provided the packagings meet the general requirements of 4.1.1.1, 4.1.1.2, and 4.1.1.4 to 4.1.1.8., This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ((-)-[R-(R*,R*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1-benzopyran.)
- Labels:
- 9
Special provisions / remarks
- Remarks:
- Special Provision 375: Environmentally Hazardous Substances/Marine Pollutants, classified under UN 3077 or UN 3082, packaged in single or combination packagings containing a net quantity per single of inner packaging of 5L or less for liquids or having a net mass per single of inner packaging of 5kg or less for solids are not subject to the ADR/RID/ADN/IMDG/IATA DGR provided the packagings meet the general requirements of 4.1.1.1, 4.1.1.2, and 4.1.1.4 to 4.1.1.8., This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ((-)-[R-(R*,R*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1-benzopyran.)
- Chemical name:
- (-)-[R-(R*,R*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1-benzopyran
- Labels:
- 9
- Marine pollutant
Special provisions / remarks
- Remarks:
- 2.10.2.7: Environmentally Hazardous Substances/Marine Pollutants, classified under UN 3077 or UN 3082, packaged in single or combination packagings containing a net quantity per single of inner packaging of 5L or less for liquids or having a net mass per single of inner packaging of 5kg or less for solids are not subject to the IMDG provided the packagings meet the general requirements of 4.1.1.1, 4.1.1.2, and 4.1.1.4 to 4.1.1.8., This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ((-)-[R-(R*,R*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1-benzopyran.)
- Chemical name:
- (-)-[R-(R*,R*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1-benzopyran
- Labels:
- 9
Special provisions / remarks
- Remarks:
- Packing instruction (passenger aircraft) : 964
Packing instruction (LQ) : Y964
Special Provision A197: Environmentally hazardous substances, classified under UN 3077 or UN 3082, when transported in single or combination packagings containing a net quantity per single or inner packaging of 5 L or less for liquids or having a net mass of 5 kg or less for solids, are not subject to any other provisions of the IATA DGR provided the packagings meet the general provisions of IATA DGR 5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.8., This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of IATA DGR §2.6.10 are met.
Additional transport information
Additional information
- Special provisions / remarks / other:
- Environmental hazards
ADN Environmentally hazardous : yes
ADR Environmentally hazardous : yes
RID Environmentally hazardous : yes
IMDG Marine pollutant : yes
IATA (Passenger)
Marine pollutant : yes
IATA (Cargo)
Marine pollutant : yes
Exposure controls / personal protection
Engineering measures: All personal protective equipment should be based on a risk assessment. Consult a Environment Health Safety expert if necessary. Engineering controls should be used as the primary means to control possible exposures. Use process enclosures, local exhaust ventilation or other engineering controls to keep exposure levels below recommended exposure limits.
Personal protective equipment
Respiratory protection: Engineering controls should always be the primary method of controlling exposures. If respiratory protective equipment is needed for certain activities, the type as well as the corresponding protection factor will depend upon the risk assessment and air concentrations, hazards, physical and warning properties of substances present. Use only respiratory protection that conforms to international/ national standards. Respirator with a vapour filter ABEK
Hand protection:
Nitrile rubber
Remarks: Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Impervious gloves
Eye protection:
Tightly fitting safety goggle
Skin and body protection:
closed work clothing chemical resistant apron, coat or coverall
Protective measures:
The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Personal protective equipment
Respiratory protection: Engineering controls should always be the primary method of controlling exposures. If respiratory protective equipment is needed for certain activities, the type as well as the corresponding protection factor will depend upon the risk assessment and air concentrations, hazards, physical and warning properties of substances present. Use only respiratory protection that conforms to international/ national standards. Respirator with a vapour filter ABEK
Hand protection:
Nitrile rubber
Remarks: Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Impervious gloves
Eye protection:
Tightly fitting safety goggle
Skin and body protection:
closed work clothing chemical resistant apron, coat or coverall
Protective measures:
The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Stability and reactivity
Reactivity: None reasonably foreseeable.
Chemical stability: Stable under recommended storage conditions.
Hazardous reactions : No dangerous reaction known under conditions of normal use.
Conditions to avoid: To avoid thermal decomposition, do not overheat. Heat, flames and sparks.
Materials to avoid: Strong Oxidizing agents.
Hazardous decomposition products: Fluorocarbons, Carbon oxides
Chemical stability: Stable under recommended storage conditions.
Hazardous reactions : No dangerous reaction known under conditions of normal use.
Conditions to avoid: To avoid thermal decomposition, do not overheat. Heat, flames and sparks.
Materials to avoid: Strong Oxidizing agents.
Hazardous decomposition products: Fluorocarbons, Carbon oxides
Disposal considerations
Waste treatment methods
Product: In accordance with National, Federal, State and Local regulations. Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities.
Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.
Product: In accordance with National, Federal, State and Local regulations. Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities.
Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
