Registration Dossier

Administrative data

First-aid measures

After inhalation:
Supply fresh air. If required, provide artificial respiration.
Consult doctor if symptoms persist.

After skin contact:
Remove contaminated clothes, wash affected area with soap and water and rinse thoroughly.
If skin irritation continues, consult a doctor.

After eye contact:
Rinse opened eye for several minutes under running water.
Then consult a doctor.

After swallowing:
Do not induce vomiting; call for medical help immediately.

Fire-fighting measures

Suitable extinguishing agents:
CO2, powder or foam

Formation of toxic gases is possible during heating or in case of fire : CO, HCl

Advice for firefighters
Protective equipment: Wear self-contained respiratory protective device.
Wear fully protective suit.

Accidental release measures

Environmental precautions:
Keep contaminated washing water and dispose of appropriately.
Do not allow to penetrate the ground/soil.

Methods and material for containment and cleaning up:
Send for recovery or disposal in suitable receptacles.

Handling and storage

Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.

Storage conditions:
Store at room temperature and dry conditions in well sealed receptacles.
Keep under nitrogen.

Transport information

Land transport (ADR/RID)

UN number:
UN3390
Proper shipping name and description:
3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. (PHOSPHORUS OXYCHLORIDE, O-DICHLOROBENZENE, MALONYL DICHLORIDE), ENVIRONMENTALLY
HAZARDOUS
Language:
English
Class:
6.1
Classification code:
TC1
Packaging group:
I
Labels:
6.1+8
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN3390
Proper shipping name and description:
TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. (PHOSPHORUS OXYCHLORIDE, ODICHLOROBENZENE, MALONYL DICHLORIDE),
MARINE POLLUTANT
Class:
6.1
Packaging group:
I
EmS code:
F-A,S-B
Labels:
6.1/8
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN3390
Proper shipping name and description:
TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S.
Class:
6.1
Packaging group:
I
Labels:
6.1(8)
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

10025-87-3 phosphoryl trichloride
WEL Short-term value: 3.8 mg/m³, 0.6 ppm
Long-term value: 1.3 mg/m³, 0.2 ppm

95-50-1 1,2-dichlorobenzene
WEL Short-term value: 306 mg/m³, 50 ppm
Long-term value: 153 mg/m³, 25 ppm
Sk

Ensure good ventilation/exhaustion at the workplace.
Use selfcontained respiratory protective device.
Wear neoprene or nitrile gloves.
The selection of the suitable gloves does not only depend on
the material, but also on further marks of quality and varies
from manufacturer to manufacturer. As the product is a
preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Wear safety goggles.
Check that an emergency eyewash facility is available near the handling zone.
Wear protective work clothing: safety shoes, apron.
Check that a security shower is available near the handling zone.

Stability and reactivity

Reactivity : no data available.
Chemical stability : no data available.
Possibility of hazardous reactions : contact with water releases toxic gases.
Conditions to avoid : moisture.
Incompatible materials : no data available.
Hazardous decomposition products : formation of toxic gases is possible during heating or in case of fire (CO, HCl).

Disposal considerations

Do not allow product to reach sewage system or any water course.
Must be specially treated adhering to official regulations.
Incineration according to regulation in force.
Do not allow to penetrate the ground/soil