Registration Dossier
Registration Dossier
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EC number: 949-159-6 | CAS number: -
Explosiveness
Administrative data
- Endpoint:
- explosive properties of explosives
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Study period:
- 2014-09-17
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- study well documented, meets generally accepted scientific principles, acceptable for assessment
- Remarks:
- No guideline is cited, but test conditions are sufficiently described. Study was conducted non-GLP. The test substance is adequately identified. Therefore validation applies with restrictions.
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 014
- Report date:
- 2014
Materials and methods
Test guideline
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- UN Manual of Tests and Criteria: Part I: Classification procedures, test methods and criteria relating to explosives of Class 1
- Version / remarks:
- DSC screening test
- Deviations:
- yes
- Remarks:
- not conducted up to 500°C
- Principles of method if other than guideline:
- DSC screening test, in accordance with UN TDG, MTC Appendix 6.
- GLP compliance:
- no
Test material
- Reference substance name:
- (E)-N-(1H-pyrazol-5-yl)-1-(thiophen-2-yl)methanimine
- EC Number:
- 949-159-6
- Molecular formula:
- C8H7N3S
- IUPAC Name:
- (E)-N-(1H-pyrazol-5-yl)-1-(thiophen-2-yl)methanimine
- Test material form:
- not specified
Constituent 1
Results and discussion
Any other information on results incl. tables
Endothermic reaction peak at ca 117°C absorbing about 80kJ/kg, followed by two exothermic reactions, with peaks at ca 184 & 253°C, releasing about 77 & 90kJ/kg.
Applicant's summary and conclusion
- Interpretation of results:
- study cannot be used for classification
- Conclusions:
- Based on Regulation (EC) N°1272/2008 (CLP) and UN MTC Appendix 6 criteria, the test was not conducted up to 500°C, and the exothermal events were below the threshold of 500 J/g.
Therefore the result is inconclusive with regard to classification. - Executive summary:
The thermal stability of the test substance was tested with Differential Thermal Analysis, in accordance with conditions recommended in UN MTC screening procedure.
Two successive exotherms were recorded, up to the maximum test temperature of 300°C, but the energy released was weak, resp. about 77 and 90 J/g.
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