Registration Dossier

Administrative data

First-aid measures

If breathed in : move person into fresh air.
Artificial respiration and/or oxygen may be necessary.
Consult a physician.
Victim to lie down in the recovery position, cover and keep him warm.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off immediately with plenty of water.
Call a physician immediately.
Wash contaminated clothing before reuse.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses.
Consult a physician.

If swallowed : rinse mouth with water (only if the person is conscious)
Call a physician immediately.

Most important symptoms and effects, both acute and delayed
Symptoms : Inhalation may provoke the following symptoms:
Dizziness
Salivation
Breathing difficulties

Skin contact may provoke the following symptoms: Pain
Blistering
Causes burns.

In case of eye contact : Pain
Causes eye burns

Indication of any immediate medical attention and special treatment needed : Treat symptomatically

Fire-fighting measures

Suitable extinguishing media : Water mist
Dry powder
Foam
Carbon dioxide (CO2)
Sand
Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.

Unsuitable extinguishing media : Water spray jet

Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus.

Further information : In the event of fire, cool tanks with water spray.

Accidental release measures

Personal precautions : Evacuate personnel to safe areas.
Isolate the area.
Prevent further leakage or spillage if safe to do so.
Ensure adequate ventilation.
Keep away from open flames, hot surfaces and sources of ignition.

Environmental precautions : Should not be released into the environment.
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up : Large spills: Dam up. Soak up with inert absorbent material. Keep in properly labelled containers.
Small spills: Gently cover the spill with an absorbent towel or pad.
Large spills + Small spills: Keep in suitable, closed containers for disposal. Treat recovered material as described in the section "Disposal considerations".

Handling and storage

Advice on safe handling : To avoid thermal decomposition, do not overheat.
Use personal protective equipment as required.
Avoid inhalation, ingestion and contact with skin and eyes.
Prevent the dangers of splashing when transferring or diluting.

Requirements for storage areas and containers : To maintain product quality, do not store in heat or direct sunlight. Store in original container. Keep containers tightly closed in a cool, well-ventilated place. Store at room temperature.

Recommended storage tem-perature : 15 - 25 °C



Transport information

Land transport (ADR/RID)

UN number:
UN2735
Proper shipping name and description:
AMINES, LIQUID, CORROSIVE, N.O.S. (dibenzylamine)
Chemical name:
Dibenzylamine
Language:
English
Class:
8
Classification code:
C7
Packaging group:
III
Labels:
8
Remarks:
Hazard Identification Number : 80
Tunnel restriction code : (E)
This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.

Inland waterway transport (ADN(R))

UN number:
UN2735
Proper shipping name and description:
AMINES, LIQUID, CORROSIVE, N.O.S.
(dibenzylamine)
Chemical name:
Dibenzylamine
Class:
8
Classification code:
C7
Packaging group:
III
Labels:
8
Remarks
This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.

Marine transport (IMDG)

UN number:
UN2735
Proper shipping name and description:
AMINES, LIQUID, CORROSIVE, N.O.S. (Dibenzylamine)
Chemical name:
Dibenzylamine
Class:
8
Packaging group:
III
EmS code:
F-A, S-B
Labels:
8
Marine pollutant
Remarks
Segregation group : alkalis
Remarks : This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.

Air transport ICAO/IATA

UN number:
UN2735
Proper shipping name and description:
Amines, liquid, corrosive, n .o.s. ( Dibenzylamine)
Chemical name:
Dibenzylamine
Class:
8
Packaging group:
III
Labels:
8
Remarks
Packing instruction (passenger aircraft) : 852
Packing instruction (LQ) : Y841
Remarks : This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of IATA DGR §2.6.10 are met.

SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering measures : All personal protective equipment should be based on a risk assessment. Consult a Environment Health Safety expert if necessary.
Engineering controls should be used as the primary means to control possible exposures. Use process enclosures, local exhaust ventilation or other engineering controls to keep exposure levels below recommended exposure limits.

Personal protective equipment
Eye protection : Face-shield

Hand protection material : Neoprene
Remarks : Impervious gloves Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).

Skin and body protection : chemical resistant apron, coat or coverall, Boots

Respiratory protection : Engineering controls should always be the primary method of controlling exposures.
If respiratory protective equipment is needed for certain activities, the type as well as the corresponding protection factor will depend upon the risk assessment and air concentrations, hazards, physical and warning properties of substances present.
Use only respiratory protection that conforms to international/ national standards.
Respirator with a vapour filter ABEK



Stability and reactivity

Reactivity : None reasonably foreseeable.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use.
Conditions to avoid : To avoid thermal decomposition, do not overheat. Heat, flames and sparks.
Incompatible materials : Strong oxidizing agents
Hazardous decomposition products : No data available

Disposal considerations

Product : Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities.
In accordance with National, Federal, State and Local regulations.

Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.