Registration Dossier

Administrative data

First-aid measures

General advice:
Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
Symptoms of poisoning may appear several hours later.
Call a physician immediately.

Protection of first-aiders:
First Aid responders should pay attention to self-protection and use the recommended protective clothing.

If inhaled:
If unconscious place in recovery position and seek medical advice.
If symptoms persist, call a physician.
If breathed in, move person into fresh air.

In case of skin contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash contaminated clothing before re-use.
If on skin, rinse well with water.
If on clothes, remove clothes.
If symptoms persist, call a physician.

In case of eye contact:
Small amounts splashed into eyes can cause irreversible tissue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed:
Keep respiratory tract clear.
Do NOT induce vomiting.
Call a physician immediately.
Rinse mouth thoroughly with water.

Fire-fighting measures

Suitable extinguishing media:
Water spray
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing media:
High volume water jet

Specific hazards during firefighting:
Contact with incompatible materials or exposure to temperatures exceeding SADT may result in a self-accelerating decomposition reaction with release of flammable vapors which may auto-ignite.
The product burns violently.
Flash back possible over considerable distance.
Vapours may form explosive mixtures with air.
Cool closed containers exposed to fire with water spray.

Special protective equipment for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.
Use personal protective equipment.

Specific extinguishing methods:
Do not use a solid water stream as it may scatter and spread fire.
Remove undamaged containers from fire area if it is safe to do so.
Use water spray to cool unopened containers.

Further information:
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Accidental release measures

Personal precautions:
Use personal protective equipment.
Avoid dust formation.
Avoid breathing dust.
Remove all sources of ignition.
Follow safe handling advice and personal protective equipment recommendations.
Never return spills in original containers for re-use.

Environmental precautions:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.

Methods for cleaning up:
Contact with incompatible substances can cause decomposition at or below SADT.
Clear spills immediately.
Suppress (knock down) gases/vapours/mists with a water spray jet.
To clean the floor and all objects contaminated by this material, use plenty of water.
Soak up with inert absorbent material.
Isolate waste and do not reuse.
Non-sparking tools should be used.
Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable.

Handling and storage

Advice on safe handling:
Do not swallow.
Do not breathe vapours/dust.
Avoid contact with skin and eyes.
Take precautionary measures against static discharges.
Never return any product to the container from which it was originally removed.
Provide sufficient air exchange and/or exhaust in work rooms.
Avoid confinement.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Smoking, eating and drinking should be prohibited in the application area.
Wash thoroughly after handling.
Protect from contamination.

Advice on protection against fire and explosion:
Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed. Keep away from heat and sources of ignition. Use only explosion-proof equipment. Keep away from combustible material.

Hygiene measures:
Keep away from food and drink. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product.

Transport information

Land transport (ADR/RID)

UN number:
UN 3116
Shippingopen allclose all
Class:
5.2
Classification code:
P2
Packaging group:
Not assigned by regulation
Labels:
5.2
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 3116
Shippingopen allclose all
Class:
5.2
Classification code:
P2
Packaging group:
Not assigned by regulation
Labels:
5.2
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 3116
Proper shipping name and description:
ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED (DISUCCINIC ACID PEROXIDE)
Class:
5.2
Packaging group:
Not assigned by regulation
EmS code:
F-F, S-R
Labels:
5.2
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
Not permitted for transport
Proper shipping name and description:
Not permitted for transport
Class:
Not permitted for transport
Packaging group:
Not permitted for transport
Labels:
Not permitted for transport
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering measures:
Minimize workplace exposure concentrations.

Personal protective equipment
Eye protection:
Tightly fitting safety goggles
Please wear suitable protective goggles. Also wear face protection if there is a splash hazard.
Ensure that eyewash stations and safety showers are close to the workstation location.

Hand protection
Material: butyl-rubber
Break through time: >= 480 min
Glove thickness: 0,5 mm

Skin and body protection:
Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential.

Respiratory protection:
In the case of dust or aerosol formation use respirator with an approved filter.
Filter type: Filter type P

Stability and reactivity

Reactivity:
Stable under recommended storage conditions.

Chemical stability:
Stable under recommended storage conditions.

Conditions to avoid:
Heat, flames and sparks.

Materials to avoid:
Accelerators, strong acids and bases, heavy metals and heavy metal salts, reducing agents

Hazardous decomposition products:
Irritant, caustic, flammable, noxious/toxic gases and vapours can develop in the case of fire and decomposition

Disposal considerations

Product:
The product should not be allowed to enter drains, water courses or the soil.
Do not contaminate ponds, waterways or ditches with chemical or used container.
Dispose of wastes in an approved waste disposal facility.

Contaminated packaging:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
Dispose of in accordance with local regulations.