Registration Dossier

Administrative data

First-aid measures

- General advice:
Take affected persons out of danger area and lay down.
Immediately remove any clothing soiled by the product.
In case of irregular breathing or respiratory arrest provide artificial respiration.
- Following inhalation:
Supply fresh air.
- Following skin contact:
Immediately rinse with water.
If skin irritation continues, consult a doctor.
- Following eye contact:
Rinse opened eye for several minutes under running water.
Remove contact lenses, if present and easy to do. Continue rinsing
- Following ingestion:
Rinse out mouth and then drink plenty of water.
- Most important symptoms and effects:
No further relevant information available.

Fire-fighting measures

- Suitable extinguishing media:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire extinguishing methods suitable to surrounding conditions.
- Unsuitable extinguishing media:
Water with full jet
- Special hazards arising from the substance or mixture:
Formation of toxic gases is possible during heating or in case of fire.
In case of fire, the following can be released:
Carbon monoxide
Carbon dioxide
Nitrogen oxides (NOx)
Sulphur oxides (SOx)
- Advice for fire fighter:
· Protective equipment: Wear self-contained respiratory protective device.
· Additional information
Cool endangered receptacles with water spray.
Collect contaminated fire fighting water separately. It must not enter the sewage system.

Accidental release measures

- Personal precautions, Protective equipment and emergency procedures:
Ensure adequate ventilation.
Wear protective equipment. Keep unprotected persons away.
Avoid formation of dust
Keep away from ignition sources
- Environmental precautions:
Do not allow product to reach sewage system or any water course.
- Methods and material for containment and cleaning up:
Pick up mechanically.
Dispose of the material collected according to regulations.

Handling and storage

- Precautions for safe handling:
Prevent formation of dust.
Any unavoidable deposit of dust must be regularly removed.
Ensure good ventilation/exhaustion at the workplace.
· Information about fire and explosion protection:
Dust can combine with air to form an explosive mixture.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
- Conditions for safe storage, including any incompatibilities:
· Requirements to be met by storerooms and receptacles: Store only in the original receptacle.
· Information about storage in one common storage facility: Store away from oxidising agents.
Storage temperature: < 30 °C (to maintain the technical properties of the product).
Incompatible products: Oxidizing agents, Water, Bases
· Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles.

Transport information

Land transport (ADR/RID)

UN number:
UN3077
Proper shipping name and description:
3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate)
Chemical name:
(S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate
Language:
English
Class:
9 Miscellaneous dangerous substances and articles.
Classification code:
9
Packaging group:
III
Labels:
9
Special Provisions:
Special marking: Symbol (fish and tree)

Inland waterway transport (ADN(R))

UN number:
UN3077
Proper shipping name and description:
3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate)
Chemical name:
(S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate
Language:
English
Class:
9 Miscellaneous dangerous substances and articles.
Classification code:
9
Packaging group:
III
Labels:
9
Remarks
Special marking: Symbol (fish and tree)

Marine transport (IMDG)

UN number:
UN3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate), MARINE POLLUTANT
Chemical name:
(S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate
Class:
9 Miscellaneous dangerous substances and articles
Packaging group:
III
EmS code:
F-A,S-F
Labels:
9
Remarksopen allclose all
Special marking: Symbol (fish and tree)
Marine pollutant = true

Air transport ICAO/IATA

UN number:
UN3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate)
Chemical name:
(S)-(4,5-dihydro-5-thioxo-1,3,4-thiadiazol-2-yl) benzenecarbothioate
Class:
9 Miscellaneous dangerous substances and articles.
Packaging group:
III
Labels:
9
Remarks
Special marking: Symbol (fish and tree)

Additional transport information

Additional transport information
Special precautions for user Warning: Miscellaneous dangerous substances and articles.
· Danger code (Kemler): 90
· EMS Number: F-A,S-F
· Stowage Category A
· Stowage Code SW23
UN "Model Regulation": UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((S)-(4,5-DIHYDRO-5-THIOXO-1,3,4-THIADIAZOL-2-YL)BENZENECARBOTHIOATE), 9, III

Exposure controls / personal protection

1. Technical protection measures
Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
2. Organisational protection measures
General protective and hygienic measures:
Do not eat, drink, smoke or sniff while working.
Keep away from foodstuffs, beverages and feed.
Store protective clothing separately.
The usual precautionary measures are to be adhered to when handling chemicals.
3. Hand protection
Protective gloves
Only use chemical-protective gloves with CE-labelling of category III.
Chemical impervious gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
4. Feet protection
No further relevant information available.
5. Body protection
Protective work clothing
6. Eye protection
Safety glasses
7. Respiratory protection
Not necessary if room is well-ventilated.

Stability and reactivity

1. Reactivity
No further relevant information available.
2. Chemical stability
No decomposition if used and stored according to specifications.
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
3. Possibility of hazardous reactions
No dangerous reactions known.
4. Conditions to avoid
No further relevant information available.
5. Incompatible materials
Strong oxidizing agents
Alkaline materials (bases)
Reacts with water
6. Hazardous decomposition products
No dangerous decomposition products known.

Disposal considerations

Waste treatment methods
· Recommendation: Must be specially treated adhering to official regulations.
Uncleaned packaging
· Recommendation: Disposal must be made according to official regulations.