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First-aid measures

Description of first aid measures
Eye contact: Get medical attention immediately. Immediately flush eyes with plenty of water,
occasionally lifting the upper and lower eyelids. Check for and remove any contact
lenses. Continue to rinse for at least 10 minutes. In case of contact with eyes, flush eyes
with plenty of water for at least 30 minutes. Chemical burns must be treated promptly
by a physician.
Inhalation: Get medical attention immediately. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours. If not breathing, if breathing is irregular or respiratory arrest
occurs, provide artificial respiration, or oxygen by a trained professional, using a pocket
type respirator.
Skin contact: In case of contact, flush skin with plenty of water for at least 30 minutes. Get medical
attention immediately. Immediately remove contaminated clothing and shoes. Wash
with plenty of soap and water. Wash contaminated clothing thoroughly with water before
removing it, or wear gloves. Wash clothing before reuse. Clean shoes thoroughly before
reuse.
Ingestion: Get medical attention immediately. Wash out mouth with water. Remove victim to fresh
air and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to drink.
Do not induce vomiting unless directed to do so by medical personnel. If vomiting
occurs, the head should be kept low so that vomit does not enter the lungs. Chemical
burns must be treated promptly by a physician. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.


Potential acute health effects
Eye contact: Causes serious eye damage.
Inhalation: May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system.
Skin contact: Harmful in contact with skin. Causes skin irritation.
Ingestion: Harmful if swallowed. May cause burns to mouth, throat and stomach.

Over-exposure signs/symptoms
Eye contact: Corrosive with symptoms of reddening, tearing, swelling, burning and possible permanent damage.
Inhalation: No specific data.
Skin contact: Corrosive with symptoms of reddening, itching, swelling, burning and possible
permanent damage.
Causes irritation with symptoms of reddening, itching, and swelling.
Ingestion: Corrosive with symptoms of coughing, burning, ulceration, and pain.
Symptoms of ingestion may include abdominal pain, nausea, vomiting, and diarrhea.

Potential chronic health effects
No known significant effects or critical hazards.
Notes to physician: Treat symptomatically. No specific treatment.
Protection of first-aiders: If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media: Use and extinguishing agent suitable for the surrounding fire. In case of fire, use water spray (fog), foam or dry chemical.
Unsuitable extinguishing media: None known.
Specific hazards arising from the chemical: Toxic and irritating gases/fumes may be given off during burning or thermal decomposition.
Hazardous thermal decomposition products: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
phosphorus oxides
metal oxide/oxides
Special protective actions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
Environmental precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up: Move containers from spill area. Approach release from upwind. Avoid dust generation.
Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a
closed, labeled waste container. Dispose of via a licensed waste disposal contractor.
Note: see ‘Identification’ Section of Safety Data Sheet for emergency contact information and ‘Disposal considerations’ Section for waste disposal. Prevent entry into sewers, water courses, basements or confined areas.

Handling and storage

Precautions for safe handling
Protective measures: Do not get in eyes or on skin or clothing. Do not ingest. Use only with adequate ventilation. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Remove contaminated clothing and protective equipment before entering eating areas. Workers should wash hands and face before eating, drinking and smoking. Put on appropriate personal protection equipment. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed.
Conditions for safe storage: Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see ‘Stability and Reactivity’ Section) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Empty containers retain product residue and can be hazardous. Do not reuse container.

Transport information

Land transport (ADR/RID)

UN number:
UN3077
Shippingopen allclose all
Class:
9
Packaging group:
III
Remarks:
8, 146, 335, A112, B54, B120, IB8, IP3, N20, N91, T1, TP33
The U.S. Department of Transportation regulations in 49CFR 172.102 permit this
material to ship as an Environmentally Hazardous Substance, Class 9, using Special Provision 146.
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN3077
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, N.O.S. (Zinc Diisopropyldithiophosphate)
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN3077
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, N.O.S. (Zinc Diisopropyldithiophosphate)
Class:
9
Packaging group:
III
Remarks
Passenger aircraft
956: 400 Kg

Cargo aircraft
956: 400 Kg
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Occupational exposure limits
Ingredient name: Zinc, bis[O,O-bis(1-methylethyl) phosphorodithioato-kS]bis(cyclohexanamine)-, (T4)-
Exposure limits: None

Appropriate engineering controls: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Personal protection
Hygiene measures:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Respiratory protection: Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Skin protection: Wear suitable protective clothing and gloves. Suitable protective footwear.
Eye/face protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face
respirator may be required instead. If contact with product is possible, wear safety
glasses with side shields.
Medical Surveillance: Not available

Stability and reactivity

Reactivity: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability: The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid: Extremes of temperature and direct sunlight.
Incompatible materials: Reducing agents, oxidizing agents, acids and bases
Hazardous decomposition products: Spontaneous decomposition may start at 150°C. After prolonged heating, slow decomposition may start at above 80°C. Formation of alkylmercaptans, dialkylsulphides,
traces of hydrogen sulphide possible.

Disposal considerations

Disposal methods: The generation of waste should be avoided or minimized wherever possible. This
material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal should be in accordance with existing federal state, provincial and or local environmental controls laws.

RCRA classification: If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40CFR 261.20-24)