Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
Remove contaminated clothing.

If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention.

On skin contact:
Wash thoroughly with soap and water. If irritation develops, seek medical attention.

On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open. If irritation develops, seek medical attention.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.

Fire-fighting measures

Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide

Advice for fire-fighters
Special protective equipment: Wear a self-contained breathing apparatus.

Further information: Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Handle in accordance with good industrial hygiene and safety practice.

Environmental precautions
Do not empty into drains.

Methods and material for containment and cleaning up
- For large amounts: Pump off product.
- For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations.

Handling and storage

Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice.
Remove contaminated clothing and protective equipment before entering eating areas.
Hands and/or face should be washed before breaks and at the end of the shift. When using do not eat, drink or smoke.

Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Conditions for safe storage, including any incompatibilities
- Segregate from acids and acid forming substances.
- Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
- Protect from direct sunlight, and from temperatures above 25 °C
- To protect product quality, maintain indicated limit temperature.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Personal protective equipment
Respiratory protection: Wear respiratory protection if ventilation is inadequate.

Hand protection: Chemical resistant protective gloves (EN 374).
- Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374), e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other materials.
- Manufacturer's directions for use should be observed because of great diversity of types.

Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166).

General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment.
Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing.
Wash contaminated clothing before reuse. Hands and/or face should be washed before breaks and at the end of the shift.

Stability and reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals with the exception of stainless steel.

Chemical stability
The product is stable if stored and handled as prescribed/indicated. The product can polymerize if the shelf life or storage temperature are greatly exceeded.

Possibility of hazardous reactions
Polymerization occurs with acids. Polymerization coupled with heat formation. May form unstable peroxides.
The product can polymerize if the shelf life or storage temperature are greatly exceeded.

Conditions to avoid
Avoid direct sunlight. Avoid heat.

Incompatible materials
Avoid contact to substances with an acid reaction, air.

Hazardous decomposition products
No hazardous decomposition products if stored and handled as prescribed/indicated.

Disposal considerations

Waste treatment methods

- Incinerate in suitable incineration plant, observing local authority regulations.
- Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.