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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
1998
Reliability:
2 (reliable with restrictions)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
1998
Report date:
1998

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: Hoechst SOP analogous Grewer oven method
Deviations:
not applicable
Principles of method if other than guideline:
Sample is heated in a wire basket.
In case of melting before any results can be seen, the substance is nixed 1 : 1 with kieselgur
GLP compliance:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
4'-chloro-2',5'-dimethoxyacetoacetanilide
EC Number:
224-638-6
EC Name:
4'-chloro-2',5'-dimethoxyacetoacetanilide
Cas Number:
4433-79-8
Molecular formula:
C12H14ClNO4
IUPAC Name:
N-(4-chloro-2,5-dimethoxyphenyl)-3-oxobutanamide

Results and discussion

Auto-ignition temperature (liquids / gases)open allclose all
Auto-ignition temperature:
> 250 °C
Atm. press.:
ca. 1 atm
Remarks on result:
other:
Auto-ignition temperature:
ca. 200 °C
Atm. press.:
ca. 1 atm
Remarks on result:
other:
Relative self-ignition temperature (solids)open allclose all
Relative self-ignition temperature:
> 250 °C
Remarks on result:
other:
Remarks:
at atm. press. of ca.1.0 atm
Relative self-ignition temperature:
ca. 200 °C
Remarks on result:
other:
Remarks:
at atm. press. of ca.1.0 atm

Any other information on results incl. tables

No self-ignition temperature, sample melts.

With Kieselguhr, self-ignition above 200 °C. This only applies to mixtures with inert medium.

Applicant's summary and conclusion

Executive summary:

Self ignition temperature of the substance in1 : 1 mixture with kieselgur is about 200 °C