Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
thermal stability
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
test procedure in accordance with national standard methods with acceptable restrictions

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2003
Report date:
2003

Materials and methods

Test guideline
Qualifier:
equivalent or similar to guideline
Guideline:
OECD Guideline 113 (Screening Test for Thermal Stability and Stability in Air)
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Benzyltris(dimethylaminato)phosphorus(1+) tetrafluoroborate(1-)
EC Number:
302-080-5
EC Name:
Benzyltris(dimethylaminato)phosphorus(1+) tetrafluoroborate(1-)
Cas Number:
94088-77-4
Molecular formula:
C13H25BF4N3P
IUPAC Name:
benzyltris(dimethylamino)phosphanium; tetrafluoroboranuide
Test material form:
solid: crystalline

Results and discussion

For thermal stability study

Test substance thermally stable:
yes
Remarks:
up to 300°C
Operating temperature
Key result
Operating temp.:
>= 30 - <= 450 °C
Sublimation:
no
Transformation products:
not measured

For study on stability to sunlight

Test substance stable to sunlight:
not determined

For study on stability to metals

Test substance stable to metals / metal ions:
not determined

Any other information on results incl. tables

The substance is thermally stable up to 300°C. Beginning at 350°C a decomposition was determined, whith an exothermal heatflow of -70 J/g. Because of the low decomposition energy adiabatic selfheating and other dangerous properties such as deflagration or shock sensitivity can be excluded.

At 147°C (Onset) an endothermal peak was detected, which can be assigned to the melting point of the substance. No other

endothermal peak was observed (no boiling point).

Applicant's summary and conclusion