Registration Dossier

Administrative data

First-aid measures

Eye contact - rinse immediately with tap water for 10 minutes - open eyelids forcibly - consult a physician if irritation persists
Skin contact - remove immediately contaminated clothes, wash affected skin with water and soap - do not use any solvents
- consult a physician if skin irritation persists
Inhalation - remove the casualty to fresh air and keep him/her calm - in the event of symptoms get medical treatment Note to physician - treat symptomatically

Fire-fighting measures

Suitable extinguishing media - water spray jet, dry powder, foam, carbon dioxide Unsuitable extinguishing media - full water jet
Specific hazards - formation of toxic and corrosive combustion gases (nitrogen oxides, sulfur oxides, hydrogen bromide
(HBr)) possible - consider dust explosion hazard
Protection of fire-fighters - chemical incident emergency response unit with full protective equipment - precipitate gases/vapours/mists with water spray
Special method of fire-fighting - cool endangered containers with water spray

Accidental release measures

Personal precautions - keep people away and stay on the upwind side
Environmental protection - do not allow to enter drains or waterways
Methods for cleaning up - take up mechanically and dispose of

Handling and storage

Handling
Technical measures - processing in closed systems, if possible superposed by inert gas (e.g. nitrogen) - local exhaust ventilation necessary - take precautionary measures against electrostatic charging - avoid dust formation; high dust explosion hazard Suitable materials - plastic, polyethylene

Storage
Storage conditions - below 40 °C - store under inert gas Validity - several months
Packaging materials - tightly closing; material: polyethylene, big bag (lined with polyethylene bag)

Transport information

Land transport (ADR/RID)

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Inland waterway transport (ADN(R))

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Marine transport (IMDG)

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Air transport ICAO/IATA

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Exposure controls / personal protection

Engineering Measures - see above

Personal protective equipment
Respiratory protection - in case of open handling of larger quantities or accidental release: particle mask or respirator with independent air supply Hand protection - protective gloves Eye protection - safety glasses

Stability and reactivity

Stability - stable under the conditions mentioned in chapter 7 Conditions to avoid - air - temperatures above 150 °C
Hazardous decomposition products
- sulphur oxides (SOx) - hydrogen bromide - nitrous oxides

Disposal considerations

Waste from residues - observe local/national regulations regarding waste disposal
- incinerate in qualified installation with flue gas scrubbing