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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Dissociation constant

Currently viewing:

Administrative data

Endpoint:
dissociation constant
Type of information:
experimental study
Adequacy of study:
key study
Study period:
no data
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Guideline study without detailed documentation, Read across to maleic anhydride

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2002

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: OECD105
Deviations:
yes
Remarks:
see below (details on methods)
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
Maleic anhydride
EC Number:
203-571-6
EC Name:
Maleic anhydride
Cas Number:
108-31-6
Molecular formula:
C4H2O3
IUPAC Name:
furan-2,5-dione
Test material form:
gas under pressure: refrigerated liquefied gas
Details on test material:
Hydrolysis to maleic acid occurs in aqueous conditions, so test substance was likely a mixture of maleic anhydride, maleic acid and its salts. Maleic acid was the analyte measured.

Results and discussion

Dissociating properties:
yes
Dissociation constantopen allclose all
No.:
#1
Temp.:
25 °C
Remarks on result:
other: K=1.14 x 10^-2 (pH = 1.94)
No.:
#2
Temp.:
25 °C
Remarks on result:
other: 5.95 x 10^-7 (pH = 6.22)

Any other information on results incl. tables

K =  1.14 x 10-2(pH = 1.94) and 5.95 x 10-7(pH = 6.22) at 25 ºC

Applicant's summary and conclusion

Conclusions:
K =  1.14 x 10-2(pH = 1.94)
K = 5.95 x 10-7(pH = 6.22) at 25 ºC