Registration Dossier

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Diss Factsheets

Administrative data

Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
3 June 2010
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study was performed according to guideline

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2010
Report date:
2010

Materials and methods

Test guideline
Qualifier:
equivalent or similar to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts
EC Number:
283-392-8
EC Name:
Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts
Cas Number:
84605-29-8
Molecular formula:
Not applicable
IUPAC Name:
Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts
Details on test material:
- Substance type: a mixture of coordination compounds in oil consisting of a zinc metal complex bonded to alkydithiophosphate ligands

Results and discussion

Auto-ignition temperature (liquids / gases)
Auto-ignition temperature:
264 °C
Atm. press.:
>= 98 - <= 100.45 kPa
Remarks on result:
other:

Any other information on results incl. tables

Table 1. Results of Auto-Flammability Test

Test Temperature

(0C)

Test Volume (µL)

Ignition Delay

(sec)

Observations

50 (clean flask)

70

> 300

No ignition

100 (clean flask)

70

> 300

No ignition

150 (clean flask)

70

> 300

No ignition

200

70

> 300

No ignition, grey fumes emitted

250

70

> 300

No ignition, grey fumes emitted

300

70

   13

Yellow flame, grey flumes emitted

290

70

> 300

No ignition, grey fumes emitted

296

70

   17

Yellow flame, grey flumes emitted

294

70

   16

Yellow flame, grey flumes emitted

292

70

   18

Yellow flame, grey flumes emitted

290 (clean flask)

70

20

Yellow flame, grey flumes emitted

282 (clean flask)

70

> 300

No ignition, grey fumes emitted

286 (clean flask)

70

> 300

No ignition, grey fumes emitted

288 (clean flask)

70

> 300

No ignition, grey fumes emitted

288 (clean flask)

200

   31

Yellow flame, grey flumes emitted

286 (clean flask)

200

   34

Yellow flame, grey flumes emitted

282

200

   33

Yellow flame, grey flumes emitted

280

200

   35

Orange flame, grey flumes emitted

278 (clean flask)

200

36

Orange flame, grey flumes emitted

276 (clean flask)

200

46

Orange flame, grey flumes emitted

272 (clean flask)

200

47

Orange flame, grey flumes emitted

268 (clean flask)

200

> 300

No ignition, grey fumes emitted

270 (clean flask)

200

46

Orange flame, grey flumes emitted

268 (clean flask)

400

91

Orange flame, grey flumes emitted

266 (clean flask)

400

90

Orange flame, grey flumes emitted

264 (clean flask)

400

93

Orange flame, grey flumes emitted

260 (clean flask)

400

> 300

No ignition, grey fumes emitted

262 (clean flask)

400

> 300

No ignition, grey fumes emitted

262 (clean flask)

600

> 300

No ignition, grey fumes emitted

262 (clean flask)

800

> 300

No ignition, grey fumes emitted

262 (clean flask)

1000

> 300

No ignition, grey fumes emitted

262 (clean flask)

1200

> 300

No ignition, grey fumes emitted

Applicant's summary and conclusion

Conclusions:
The auto-ignition temperature of the substance is 264 degrees C
Executive summary:

The auto-ignition temperature of the substance was determined using a method designed to be compatible with EU Method A.15. Varying amounts of the substance were heated in a flask and observed for signs of ignition over a 300 second period until the lowest temperature at which ignition occured was determined.

The auto-ignition temperature of the test substance was determined to be 264 degrees C at atmospheric pressures between 98.00 - 100.45 kPa.