Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Phototransformation in air

Currently viewing:

Administrative data

Endpoint:
phototransformation in air
Type of information:
experimental study
Adequacy of study:
supporting study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Estimated data based on calculations.

Data source

Reference
Reference Type:
publication
Title:
Environmental Risk Evaluation Report: Long-Chain Chlorinated Paraffins.
Author:
UK Environment Agency
Year:
2009

Materials and methods

Principles of method if other than guideline:
calculated (Syracuse Research Corporation AOP (version 1.86 based on Atkinson)
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Paraffin waxes and Hydrocarbon waxes, chloro
EC Number:
264-150-0
EC Name:
Paraffin waxes and Hydrocarbon waxes, chloro
Cas Number:
63449-39-8
Molecular formula:
C18H33Cl5 C18H30Cl8 C20H36Cl6 C20H33Cl9 C25H45Cl7 C25H42Cl10 C25H29C23 C30H53Cl9 C30H49Cl13 C30H35Cl27
IUPAC Name:
Paraffin waxes and Hydrocarbon waxes (C18 and longer), chloro
Details on test material:
C20-30, 70.8-71.3% Cl (solid)

Study design

Estimation method (if used):
Model
Light source:
sunlight
Details on light source:
sunlight; model data
Details on test conditions:
hydroxyl radical concentration of 5x10E5 molecule/cm3
Reference substance:
no

Results and discussion

Preliminary study:
Not applicable
Test performance:
Not applicable
Dissipation half-life of parent compoundopen allclose all
DT50:
112 h
Test condition:
C25 (71.3% Cl wt); hydroxyl radical concentration of 5x10E5 molecule/cm3
DT50:
69.9 h
Test condition:
C30 (70.8% Cl wt); hydroxyl radical concentration of 5x10E5 molecule/cm3
Transformation products:
not specified
Results with reference substance:
No data

Any other information on results incl. tables

Estimated atmospheric half-lives are based are based on atmospheric hydroxyl radical concentration of 5x105 molecule/cm3.

Formula

Chlorine Content

(% wt. Cl)

kOH

(cm^3/molecule s)

Atmospheric half-life

(hours)

C25H29Cl23

71.3

3.43 x 10-12

112

C30H35Cl27

70.8

5.51 x 10-12

69.9

Applicant's summary and conclusion

Validity criteria fulfilled:
not applicable
Conclusions:
Estimated atmospheric halves in the range of 70-112 hrs for >70% Cl (wt.) LCCP components.
Executive summary:

Estimated atmospheric halves in the range of 70-112 hrs for >70% Cl (wt.) LCCP components.