Registration Dossier
Registration Dossier
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EC number: 209-143-5 | CAS number: 556-88-7
Guidance on Safe Use
Administrative data
First-aid measures
4.1 Description of first aid measures
General advice:
Helpers must protect themselves and bring victims out of hazard area. Seek medical advice in case of symptoms caused by eye or skin contact, inhalation or swallowing.
If inhaled:
Move to fresh air.
In case of skin contact:
Change contaminated clothing.
Wash off with plenty of water and soap.
In case of eye contact:
Rinse thoroughly with plenty of water, also under the eyelids.
If swallowed:
Clean mouth with water and drink afterwards plenty of water.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms:
To the best of our knowledge, experiences about acute systemic health effects in human beings are not available.
Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media:
water spray
Carbon dioxide (CO2)
Foam
Unsuitable extinguishing media:
high volume water jet
5.2 Special hazards arising from the substance or mixture
Hazardous combustion products:
Ammonia
Carbon oxides
nitrous gases
5.3 Advice for firefighters
Special protective equipment for firefighters:
In the case of fire, wear respiratory protective equipment in-dependent of surrounding air and chemical protective suit.
Further information:
With large-scale fire, violent decomposition or even explosion is possible.
Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions:
Wear personal protective equipment; see section 8.
Avoid formation of dust. Ensure sufficient ventilation.
Keep away from heat and sources of ignition.
Assure sufficient ventilation.
Avoid dust formation.
Avoid contact with hot surfaces
6.2 Environmental precautions
Environmental precautions:
Product or extinguishing water with product must not be al-lowed to enter soil, sewers or natural bodies of water.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up:
Use mechanical handling equipment.
Protect from spark formation.
Avoid dust formation.
Keep in suitable, closed containers for disposal.
After cleaning, flush away traces with water.
6.4 Reference to other sections
For disposal considerations see section 13.
Handling and storage
7.1 Precautions for safe handling
Advice on safe handling:
Provide sufficient ventilation and exhaust at the workplace.
Handle and open container with care.
Prevent dust formation.
Advice on protection against fire and explosion:
Avoid formation of air-dust mixtures and keep away from ignition sources (sparks, flames, open flame) to prevent dust ex-plosions. Keep away from heat. Avoid impact and friction.
Hygiene measures:
Do not breathe dust. Avoid contact with skin, eyes and clothing. Take off contaminated clothing and shoes immediately. Wash contaminated clothing before re-use. Do not eat, drink or smoke while working. Wash hands, and/or face before breaks and when workday is finished. Keep away from food, drink and animal feedingstuffs.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Keep containers tightly closed in a dry, cool and well-ventilated place.
Advice on common storage:
Keep away from oxidizing agents, strongly alkaline and strong-ly acid materials in order to avoid exothermic reactions.
Storage class (TRGS 510):1, Explosive hazardous materials
Dampness:
Keep in a dry place.
Further information on storage stability:
Keep away from heat.
Packaging material:
Unsuitable material: Metal
7.3 Specific end use(s)
Specific use(s):
We are unaware of any specific end uses which go beyond the data reported in Section 1.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 0282
Shipping information
- Proper shipping name and description:
- NITROGUANIDINE (PICRITE)
- Chemical name:
- 1-nitroguanidine
- Language:
- English
- Class or division:
- Class 1: Explosives; Division 1.1
- Compatibility group:
- D
- Labels:
- 1.1D
Special provisions / remarks
- Special provisions:
- Observe listed materials regulation §35, paragraph 1 GGVSEB
Tunnel restriction code (B1000C)
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 0282
Shipping information
- Proper shipping name and description:
- NITROGUANIDINE (PICRITE)
- Chemical name:
- 1-nitroguanidine
- Language:
- English
- Class or division:
- Class 1: Explosives; Division 1.1
- Labels:
- 1.1D
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 0282
Shipping information
- Proper shipping name and description:
- NITROGUANIDINE (PICRITE)
- Chemical name:
- 1-nitroguanidine
- Language:
- English
- Class or division:
- Class 1: Explosives; Division 1.1
- Compatibility group:
- D
- EmS code:
- F-B
- S-Y
- Labels:
- 1.1D
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- not permitted
Shippingopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Worker Inhalation Long-term - systemic effects 164 mg/m3
Worker Inhalation Acute - systemic effects 823 mg/m3
Worker dermal Long-term - systemic effects 23,3 mg/kg body-weight/day
Worker dermal Acute - systemic effects 116,5 mg/kg body-weight/day
Consumers Inhalation Long-term - systemic effects 29 mg/m3
Consumers dermal Long-term - systemic effect 8,3 mg/kg body-weight/day
Consumers Oral Long-term - systemic effects 8,3 mg/kg body-weight/day
Freshwater 0,044 mg/l
marine water 0,0044 mg/l
sewage treatment plant 30 mg/l
Fresh water sediment 0,1 mg/kg dry weight (d.w.)
Marine sediment 0,01 mg/kg dry weight (d.w.)
soil 0,016 mg/kg dry weight (d.w.)
oral (secondary poisoning) 37 mg/kg dietary
8.2 Exposure controls
Personal protective equipment
Eye protection:
Safety glasses
Hand protection
Material:
Nitrile rubber, Recommendation: Camatril 730
Break through time:> 480 min
Glove thickness:0,4 mm
Material:
Chloroprene, Recommendation: Camapren 722
Break through time:> 480 min
Glove thickness:0,6 mm
Skin and body protection:
Protective clothing
Respiratory protection:
not required under normal use
Use suitable respiratory protection in the presence of dust.
Dust protection mask in accordance with EN 149 FFP2
Stability and reactivity
10.1 Reactivity
See section 10.3
10.2 Chemical stability
No decomposition if stored and applied as directed.
10.3 Possibility of hazardous reactions
Hazardous reactions:
Danger of decomposition under influence of heat. Exothermic reaction with concentrated sulphuric acid Violent reaction with oxidizing agents. Explosive when dry.
10.4 Conditions to avoid
Conditions to avoid:
temperatures > 75 °C
To avoid thermal decomposition, do not overheat.
Keep away from direct sunlight.
10.5 Incompatible materials
Materials to avoid:
acids, bases, oxidizing agents
Amines
conc. sulfuric acid
Heavy metal salts
Silver and mercury salts
10.6 Hazardous decomposition products
decomposition products In the case of fire see section 5
Disposal considerations
13.1 Waste treatment methods
Product:
Must be brought to an adequate waste treatment facility, in conformity with applicable waste disposal regulations.
Contaminated packaging:
Packaging, that can not be reused after cleaning must be disposed or recycled in accordance with all federal, national and local regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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