Registration Dossier

Administrative data

First-aid measures

. After inhalation:
Supply fresh air; consult doctor in case of complaints.
. After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
. After eye contact:
Rinse opened eye for several minutes under running water. If symptoms
persist, consult a doctor.
. After swallowing:
If symptoms persist consult doctor.

Fire-fighting measures

. Suitable extinguishing agents :
CO2, powder or water spray. Fight larger fire with alcohol resistant
foam.
. For safety reasons unsuitable extinguishing agents :
Water with full jet
. Special hazards, products of combustion, released gases :
In case of fire, the following can be released:
Carbon monoxide and carbon dioxide
. Special protective equipment :
Mouth respiratory protective device.
Wear protective clothing.
. Additional information :
Cool endangered receptacles with water spray.

Accidental release measures

. Person-related safety precautions:
Particular danger of slipping on leaked/spilled product.
See Section 8 for information on personal protection equipment.
. Measures for environmental protection:
Do not allow product to reach sewage system or any water course.
Keep contaminated washing water and dispose of appropriately.
. Measures for cleaning/collecting:
Pick up mechanically.
Send for recovery or disposal in suitable receptacles.
Clean the affected area carefully; suitable cleaners are:
Warm water
Warm water and cleansing agent
. Additional information:
See Section 13 for disposal information.

Handling and storage

. Handling:
. Information for safe handling:
See Section 8 for information on personal protection equipment.
. Storage:
. Requirements to be met by storerooms and receptacles:
Protect from heat and direct sunlight.
Keep receptacle tightly sealed.
Use polyolefine receptacles (made out of plastic).
. Recommended storage temperature:
< 40°C

Transport information

Shippingopen allclose all
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

Shippingopen allclose all
Remarks
not regulated

Marine transport (IMDG)

Remarks
not regulated

Air transport ICAO/IATA

Remarks
not regulated
SpecialProvisionsopen allclose all

Exposure controls / personal protection

. Additional information about design of technical facilities:
Eye wash facility and security showers nearby.
. DNELs
ACUTE TOXICITY = Not required
IRRITATION/CORROSIVITY = Not applicable
SENSITISATION = Not applicable
LONG-TERM - SYSTEMIC EFFECTS:
- Repeated dose toxicity: sub-acute =
Oral = Not applicable
and, by extrapolation:
Dermal = 3,33 mg/kg/day
Inhalation = 23,5 mg/m3
- Mutagenicity = Not applicable and useless
- Carcinogenicity = Not applicable and useless
- Reproductive toxicity fertility impairment =
Oral route = Not applicable
and, by extrapolation:
Dermal = 3,33 mg/kg/day (systemic)
Inhalation = 23,5 mg/m3 (systemic)
- Reproductive toxicity developmental toxicity =
Oral route = Not applicable
and, by extrapolation:
Dermal = 1,11 mg/kg/day (systemic)
Inhalation = 7,84 mg/m3 (systemic)
. PNECs
aqua - fresh water = 0,1 mg/l
aqua - marine water = 0,01 mg/l
aqua - water, intermittent = 1 mg/l
sediment = 927 mg/kg
soil = not required, because the substance is readily biodegradable.
atmosphere = not required, because the substance is readily
biodegradable
sewage treatment systems = not required, because the substance is
readily biodegradable
. Personal protective equipment:
. General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Wash contaminated clothing before re-use.
Storing food in the working area is prohibited.
Keep away from foodstuffs, beverages and feed.
Do not eat, drink or smoke while working.
. Protection of hands:
Protective gloves
. Material of gloves
The selection of the suitable gloves does not only depend on the
material, but also on further marks of quality and varies from
manufacturer to manufacturer.
. Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of
the protective gloves and has to be observed.
. Eye protection:
Safety glasses
. Body protection:
Use protective suit.
. Risk management measures
Product not classified as dangerous.
The following risk management measures are those implemented as a
standard in SEPPIC facilities. Although they are applied, they are not
actually mandatory for this particular substance. Indeed the substance
is devoid of significant hazard properties as demanstrated along the
CSR, so that exposure and risk assessments are not required.
-Risk management measures ans operational conditions related to
human exposure:
The synthesis takes place in a closed system. Potential exposure
is limited to the solid substance, during selected tasks occuring in
an open system (such as sampling). There is no exposure to a powder or
an aerosol and the type of exposure is non-dispersive. Personal
protective equipment includes gloves, safety glasses and protective
clothing.
-Risk management measures and operational conditions related to
environmental exposure:
The synthesis occurs in a closed system. Solid wastes are
incinerated in dedicated incineration centres. Wastewater is treated
in SEPPIC's on-site sewage treatment plants, and the resulting treated
wastewater is directed to public sewage treatment plants.
Product not classified as dangerous.
Exposure scenarios are not required.

Stability and reactivity

. Thermal decomposition / conditions to be avoided:
Stable at environment temperature.
. Dangerous decomposition products:
Carbon monoxide
. Additional information:
Stability in organic solvents and identity of relevant degradation
products: not determined.

Disposal considerations

. Product:
. Recommendation:
Disposal must be made according to official regulations.
. Uncleaned packaging:
. Recommendation:
Disposal must be made according to official regulations.
Packagings that may not be cleansed are to be disposed of in the same
manner as the product.