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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Water solubility

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
water solubility
Type of information:
experimental study
Adequacy of study:
key study
Study period:
26 Jul 2012
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.6 (Water Solubility)
Qualifier:
according to guideline
Guideline:
OECD Guideline 105 (Water Solubility)
GLP compliance:
no
Type of method:
flask method
Water solubility:
> 250 g/L
Temp.:
20 °C
pH:
5.4

Preliminary test:

Aliquot

Weighed sample, g

A

2.46

B

2.03

Sum

4.49

While being added to the water, solutions with increasing viscosity were being formed, resulting in a gel after the addition of 4.49 g of the test item.

With 4.49 g of test item being mixed into 10 g of water, a gel with a total weight of 14.5 g has been formed. This is equivalent to 31% (w/w) of test item in solution/gel.

As the water density will significantly increase with addition of the test item, it can be concluded that water solubility is about 310 g/L, resulting in a gel. Due to the fact that the formation of the gel is a continuous process and no discrete point can be identified at which dissolution in water switches to gelling, the water solubility can be approximated to > 310 g/L.

Conclusions:
Interpretation of results (migrated information): miscible

Description of key information

> 250 g/L at 20 °C, pH = 5.4

Key value for chemical safety assessment

Additional information

The water solubility of the substance was determined according to EU Method A.6 and OECD 105 (flask method). Gel formation at concentrations > 310 g/L was observed.