Reaction Mass of 1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,4,5,6,7,8-octahydroazulene and 3,8-dimethyl-5-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene and 4,8a,9,9-tetramethyldecahydro-1,6-methanonaphthalen-1-ol

Guidance on Safe Use

First-aid measures

-- Description of first aid measures --

General advice

- Move out of dangerous area.

- Show this safety data sheet to the doctor in attendance.

- Symptoms of poisoning may only appear several hours later.

- Do not leave the victim unattended.

 

If inhaled

- Move to fresh air.

- If unconscious place in recovery position and seek medical advice.

- If symptoms persist, call a physician.

 

In case of skin contact

- If on skin, rinse well with water.

 

In case of eye contact

- Remove contact lenses. 

- Immediately flush eyes for at least 15 minutes. Get medical attention. 

 

If swallowed

- Keep respiratory tract clear.

- Do NOT induce vomiting.

- Do not give milk or alcoholic beverages.

- Never give anything by mouth to an unconscious person.

- Take victim immediately to hospital.

Fire-fighting measures

-- Extinguishing media --

Suitable extinguishing media

- Dry chemical

- Alcohol-resistant foam

- Carbon dioxide (CO2)

- Water spray

 

Unsuitable extinguishing media

- High volume water jet

 

-- Special hazards arising from the substance or mixture --

Specific hazards during firefighting

- Do not allow run-off from fire fighting to enter drains or water courses.

 

-- Advice for firefighters --

Special protective equipment for firefighters

- Wear self contained breathing apparatus for fire fighting if necessary.

 

Further information

- Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
- Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

-- Personal precautions, protective equipment and emergency procedures --

Personal precautions

- Use personal protective equipment.

- Ensure adequate ventilation.

 

-- Environmental precautions --

Environmental precautions

- Prevent product from entering drains.

- If the product contaminates rivers and lakes or drains inform respective authorities.

 

-- Methods and materials for containment and cleaning up --

Methods for cleaning up

- Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

- Keep in suitable, closed containers for disposal.

Handling and storage

-- Precautions for safe handling --

Advice on safe handling

- Do not breathe vapours/dust.

- Avoid exposure - obtain special instructions before use.

- Avoid contact with skin and eyes.

- For personal protection see section Exposure controls/personal protection

- Smoking, eating and drinking should be prohibited in the application area.

- Dispose of rinse water in accordance with local and national regulations.

 

Advice on protection against

- Normal measures for preventive fire protection.

 

-- Conditions for safe storage, including any incompatibilities --

Requirements for storage areas and containers

- Keep container tightly closed in a dry and well-ventilated place.

- Containers which are opened must be carefully resealed and kept upright to prevent leakage.

- Electrical installations / working materials must comply with the technological safety standards. 

 

Further information on storage conditions

- Ambient / 10-30°C (50-85°F)

- Dry, well ventilated, preferably full, hermetically sealed

 

Advice on common storage

- Protect against light.

 

Storage class (TRGS 510)

- 10 Combustible liquids

 

Other data

- No decomposition if stored and applied as directed.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3082

Shipping information

Proper shipping name and description:

ADR and RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID N.O.S.
(octahydrotetramethyl methano-1-naphthol, beta-Pinene)

Chemical name:

Reaction Mass of 1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,4,5,6,7,8-octahydroazulene and 3,8-dimethyl-5-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene and 4,8a,9,9-tetramethyldecahydro-1,6-methanonaphthalen-1-ol

Language:

English

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

SpecialProvisions

SpecialProvisions 1

Special provisions:

Environmentally hazardous : yes

SpecialProvisions 2

Special provisions:

Special precautions for user / ADR:
Tunnel restriction code : (-)

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3082

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(octahydrotetramethyl methano-1-naphthol, beta-Pinene)

Chemical name:

Reaction Mass of 1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,4,5,6,7,8-octahydroazulene and 3,8-dimethyl-5-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene and 4,8a,9,9-tetramethyldecahydro-1,6-methanonaphthalen-1-ol

Language:

English

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Marine pollutant

Special provisions / remarks

Special provisions:

IMDG Code Segregation : None

Air transport (UN RTDG/ICAO/IATA)

UN number:

3082

Shipping information

Proper shipping name and description:

Environmentally hazardous substance, liquid, n.o.s.
(octahydrotetramethyl methano-1-naphthol, beta-Pinene)

Chemical name:

Reaction Mass of 1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,4,5,6,7,8-octahydroazulene and 3,8-dimethyl-5-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene and 4,8a,9,9-tetramethyldecahydro-1,6-methanonaphthalen-1-ol

Language:

English

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Special provisions / remarks

Special provisions:

IATA (Passenger and Cargo)
Environmentally hazardous : yes

SpecialProvisions

Exposure controls / personal protection

-- Control parameters --

Contains no substances with occupational exposure limit values.

 

-- Exposure controls --

Exposure assessment: Exposures are dependent on the product being handled, the potential for chemical release, and any resulting airborne concentrations or dermal contact. Since product handling and release scenarios vary, and no two workplaces are exactly alike, it is recommended that the potential for exposure be assessed prior to the product’s use or introduction. Exposure assessments should be performed by an occupational hygienist, industrial hygienist, or other qualified occupational or environmental health professional. An exposure assessment should be conducted to determine the efficacy of any ventilation and the need for additional PPE. The PPE indicated below are recommendations for worst-case scenario exposures. An exposure assessment will identify more applicable measures to be implemented. EN and ANSI standards are mentioned in the following recommendations, consult equivalent local standards when required.
PPE is always the last resort to avoid exposure. In any case technical and organisational measures have to be explored and used prior to the selection of PPE. The PPE selection is for operators trained to work with chemicals according to good industrial hygiene and safety practice. Operators have to be trained on the use of PPE.

 

- Engineering measures

Use engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use the product only with adequate ventilation.

 

- Personal protective equipment

* Eye/face protection: Use safety goggles tested according to EN 166/ ANSI Z87.1 or equivalent local standard. 

* Hand protection: Use gloves when handling substance in open systems.
Inspect gloves prior to use. Train operators for proper use.If only incidental exposure is expected: (work without direct contact to substance) use gloves tested according EN 16523-1/ASTM F739 or equivalent local standard breakthrough times at least 10 minutes. Change gloves frequently.
If direct skin contact is expected: use gloves tested according to EN 16523-1/ASTM F739 or equivalent local standard.
Permeation time must exceed contact time.

* Other skin protection: Wear working clothes covering arms and legs.
The type of protective equipment must be selected according to the concentration and amount of the hazardous substance at the specific workplace. Use apron and sleeve covers or complete chemical suit if exposure is expected. 

* Respiratory protection: Respiratory protection should be worn when workplace exposures exceed exposure limit requirements or guidelines.
If there are no applicable exposure limits or guidelines, use an approved respirator where there is a potential for adverse effects, including but not limited to respiratory irritation or odor, or where indicated by the exposure assessment. Selection of air-purifying or positive-pressure supplied-air will depend on the results of the exposure assessment which includes an evaluation of the specific operations and the potential airborne concentrations. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus.

In case a risk analysis proved the cartridge respirator as acceptable, use type: ABEK-P3 (EN 14387) OR Combination Multi-gas/P100 (42CFR84.193; ANSI Z88.7 or equivalent local standard) as a backup to engineering controls.

In absence of engineering controls, use self-contained breathing apparatus or full face supplied air respirators.
Use respirators and components tested and approved under appropriate government standards such as CEN (EU) or NIOSH 42 CFR 84(US).

* Thermal hazards: Wear appropriate thermal protective clothing, when necessary.

* Hygiene measures: Remove contaminated clothing and protective equipment before entering eating areas.
Do not eat, drink or smoke during work. Wash hands any time after handling the product. 

 

- Environmental exposure controls 

General advice: Prevent product from entering drains.
If the product contaminates rivers and lakes or drains inform respective authorities.

Stability and reactivity

-- Reactivity --

none

 

-- Chemical stability --

The product is chemically stable.

 

-- Possibility of hazardous reactions --

- Hazardous reactions: No decomposition if stored and applied as directed.

Disposal considerations

-- Waste treatment methods --

Product

- The product should not be allowed to enter drains, water courses or the soil.
- Do not contaminate ponds, waterways or ditches with chemical or used container.
- Send to a licensed waste management company.

 

Contaminated packaging 

- Empty remaining contents.

- Dispose of as unused product.

- Do not re-use empty containers.

 

Dispose of in accordance with local regulations.