Registration Dossier
Registration Dossier
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EC number: 213-736-4 | CAS number: 1005-56-7
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
If inhaled : If breathed in, move person into fresh air
Victim to lie down in the recovery position, cover and keep him warm.
Artificial respiration and/or oxygen may be necessary.
Consult a physician.
In case of skin contact : Remove all contaminated clothing under the shower.
Keep warm and in a quiet place.
Wash off immediately with plenty of water.
Call a physician immediately.
Wash contaminated clothing before re-use.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses.
Consult a physician.
If swallowed : If swallowed, rinse mouth with water (only if the person is conscious).
Drink plenty of water.
Do NOT induce vomiting.
Take victim immediately to hospital.
Most important symptoms and effects, both acute and delayed
Risks : No information available.
Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media : Water mist
Dry powder
Foam
Carbon dioxide (CO2)
Sand
Aqueous film forming foam (AFFF).
Unsuitable extinguishing media: Water spray jet
Special hazards arising from the substance or mixture
Hazardous combustion products: Carbon oxides
Sulphur oxides
Hydrogen chloride gas
Advice for firefighters
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
Firefighters must wear fire resistant personal protective equipment.
Further information : In the event of fire, cool tanks with water spray.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions : Evacuate personnel to safe areas.
Isolate the area.
Ensure adequate ventilation.
Prevent further leakage or spillage if safe to do so.
Keep away from heat and sources of ignition.
Environmental precautions
Environmental precautions : Should not be released into the environment.
Methods and material for containment and cleaning up
Methods for cleaning up : Soak up with inert absorbent material and dispose of as hazardous waste.
Reference to other sections
For disposal information, see section 13, Refer to protective measures listed in sections 7 and 8
Handling and storage
Precautions for safe handling
Advice on safe handling : To avoid thermal decomposition, do not overheat.
Prevent the dangers of splashing when transferring or diluting.
Do not breathe vapours or spray mist.
Keep away from heat and sources of ignition.
Use personal protective equipment as required.
Advice on protection against fire and explosion: Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Vapours may form explosive mixtures with air.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers: Store at room temperature.
Recommended storage temperature: 15 - 25 °C
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3265
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(phenyl thioxochloroformate) - Chemical name:
- (phenyl thioxochloroformate)
- Class or division:
- Class 8: Corrosive substances
- Packing group:
- Packing group II: Substances presenting medium danger
- Labels:
- 8
Special provisions / remarks
- Special provisions:
- Packing group : II
Classification Code : C3
Hazard Identification Number : 80
Labels : 8
Tunnel restriction code : (E) - Remarks:
- This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG
§3.5.1.4 are met.
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3265
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(phenyl thioxochloroformate) - Chemical name:
- (phenyl thioxochloroformate)
- Class or division:
- Class 8: Corrosive substances
- Packing group:
- Packing group II: Substances presenting medium danger
- Labels:
- 8
Special provisions / remarks
- Special provisions:
- Packing group : II
Classification Code : C3
Hazard Identification Number : 80
Labels : 8 - Remarks:
- This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3265
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(phenyl thioxochloroformate) - Chemical name:
- (phenyl thioxochloroformate)
- Class or division:
- Class 8: Corrosive substances
- Packing group:
- Packing group II: Substances presenting medium danger
- EmS code:
- F-A
- S-B
- Labels:
- 8
Special provisions / remarks
- Special provisions:
- Packing group : II
Labels : 8
EmS Code : F-A, S-B
Segregation group : Acids (SGG1) - Remarks:
- This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3265
Shipping information
- Proper shipping name and description:
- Corrosive liquid, acidic, organic, n.o.s.
(phenyl thioxochloroformate) - Chemical name:
- (phenyl thioxochloroformate)
- Class or division:
- Class 8: Corrosive substances
- Packing group:
- Packing group II: Substances presenting medium danger
- Labels:
- 8
Special provisions / remarks
- Special provisions:
- Packing instruction (cargo aircraft): 855
Packing instruction (LQ) : Y840
Packing instruction (EQ) : E2
Packing group : II
Labels : 8
Packing instruction (passenger aircraft): 851
Packing instruction (LQ) : Y840
Packing group : II
Labels : 8 - Remarks:
- This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of IATA DGR §2.6.10 are met.
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Exposure controls / personal protection
Engineering measures
All personal protective equipment should be based on a risk assessment. Consult a Environment Health Safety expert if necessary.
Engineering controls should be used as the primary means to control possible exposures. Use process enclosures, local exhaust ventilation or other engineering controls to keep exposure
levels below recommended exposure limits.
Personal protective equipment
Eye protection : Face-shield
Hand protection
Remarks : Take note of the information given by the producer concerning permeability and break through times, and of
special workplace conditions (mechanical strain, duration of contact).
Impervious gloves
Neoprene gloves
Skin and body protection : chemical resistant apron, coat or coverall
Boots
Respiratory protection : Engineering controls should always be the primary method of controlling exposures.
If respiratory protective equipment is needed for certain activities, the type as well as the corresponding protection factor will depend upon the risk assessment and air concentrations, hazards, physical and warning properties of substances present.
Use only respiratory protection that conforms to international/national standards.
Respirator with a vapour filter
ABEK
Protective measures : The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Ensure that eye flushing systems and safety showers are located close to the working place
Stability and reactivity
Reactivity
None reasonably foreseeable.
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
Hazardous reactions : No data available
Conditions to avoid
Conditions to avoid : Protect from frost, heat and sunlight.
Incompatible materials
Materials to avoid : Oxidizing agents
Hazardous decomposition products
None known.
Disposal considerations
Waste treatment methods
Product : In accordance with local and national regulations
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
