Registration Dossier
Registration Dossier
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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
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EC number: 200-372-6 | CAS number: 58-27-5
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
General information:
Consult a physician. Show the safety data sheet to the doctor in attendance.
Inhalation:
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
Skin contact:
Wash off with soap and plenty of water.Consult a physician.
Eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Ingestion:
Never give anything by mouth to an unconscious person.Rinse mouth with water.Consult a physician.
Fire-fighting measures
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture:
Very high dust explosion hazard.
In case of fire, product may form irritant menadione vapors and toxic fumes such as CO.
Advice for firefighters:
Wear self contained breathing apparatus for fire fighting if necessary. Precipitate gases/vapours/mists with water spray.
Accidental release measures
Personal precautions,protective equipment and emergency procedures:
Use personal protective equipment according to the circumstances.
Collect spilled solid material avoiding dust formation.
Avoid breathing vapors, mist or gas.
Ensure adequate ventilation.
Evacuate personnel to safe areas.
Avoid breathing dust.
Environmental precautions:
Do not let product enter drains.
Methods and materials for containment and cleaning up:
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal in compliance with law.
Handling and storage
Precautions for safe handling:
When handling apply local exhaust ventilation.
Avoid formation of dust and aerosols; very high dust explosion hazard.
Take precautionary measures against electrostatic charging.
Wear protective equipment.
Avoid contact with eyes and skin.
Wash thoroughly with cold water after handling.
Conditions for safe storage:
Keep containers tightly closed and away from heat. Store in cool, dry and well ventilated place.
Avoid heat and light exposure, store separate from basic substances.
Standard packaging: carton boxes with inner polyethylene bag.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not regulated
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3077
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Marine transport (UN RTDG/IMDG)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance,
solid, n.o.s (Menadione) - Chemical name:
- Menadione
- Labels:
- 9
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance,
solid, n.o.s (Menadione) - Chemical name:
- Menadione
- Labels:
- 9
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Exposure controls / personal protection
Appropriate engineering controls:
Install local dust collection device and overall ventilation device in the workplace, minimize the exposure opportunities to contact the product as far as possible.
Control parameters:
Components with workplace control parameters.
Average allowed concentration in eight-hour working day / Maximum allowed concentration in short exposure: No data available
Biological indicators: No data available
Personal protective equipment and measurement:
Respiratory protection: particulate dust respirator.
Hand protection: industrial quality gloves (PVC, rubber).
Eye protection: safety goggles with side-shields, face shield and eye-cleaning equipment.
Body protection: Complete suit protecting against chemicals and preventing penetration.
Hygiene measures: avoid the bare parts of the body to contact the product, don’t wear contaminated clothing, banded to eat, drink and smoke at workplace after working.
Environmental exposure controls:
No data available
Stability and reactivity
Conditions to avoid:
The product is stable under the suggested handling and storage conditions not causing dangerous reactions.
Materials to avoid:
Strong oxidising agents, strong acids, strong alkalis and iron container.
Hazardous decomposition products:
Irritant menadione vapours and fumes containing CO, CO2, are produced respectively by thermal decomposition or when the product burns.
Disposal considerations
Disposal methods of the substance/preparation:
Whatever cannot be saved for recovery or recycling should be managed in an appropriate waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations.
Disposal methods of the contaminated packaging:
Dispose of contaminated packaging and unused materials in accordance with federal, state and local requirements.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.