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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
04 May 2020 til 29 July 2020
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2020
Report date:
2020

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Deviations:
no
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
Iron(III) manganese(II) hexacyanoferrate(II) sodium salts
EC Number:
847-973-5
Cas Number:
2363126-51-4
Molecular formula:
NaxMny1Fey2[Fe(CN)6]z X = 1-2; Y1 = 0.5-0.9; Y2 = 0.1-0.5; Z = 0.67-1.0
IUPAC Name:
Iron(III) manganese(II) hexacyanoferrate(II) sodium salts
impurity 1
Chemical structure
Reference substance name:
Water
EC Number:
231-791-2
EC Name:
Water
Cas Number:
7732-18-5
Molecular formula:
H2O
IUPAC Name:
Water
Test material form:
solid: particulate/powder
Specific details on test material used for the study:
See section on test material

Results and discussion

Relative self-ignition temperature (solids)
Key result
Relative self-ignition temperature:
233 °C

Any other information on results incl. tables

In the preliminary test no flame was recongised, but a glowing red reaction propagated over 200 mm in 15 minutes 28 seconds.

The result of the preliminary screening test obviated the need to perform the main test.

The test item was a blue powder. Whilst heating the test item, self-heating of the sample was observed. The temperature/time curve is shown as Figure 1. On completion of the test, the test item was fused grey granules.

Applicant's summary and conclusion

Conclusions:
The test item has been determined to have a relative self-ignition temperature of 233 °C.