Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: Remove to fresh air. Seek medical advice.
Emergency measure - Eyes: Rinse immediately with plenty of water. Seek medical
advice.
Emergency measure - Skin: Remove contaminated clothes and launder before using again.


Rinse area thoroughly with plenty of water. Seek medical
advice.
Emergency measure - Ingestion: Drink copious amounts of water. Seek medical advice. Show
label where possible.

Fire-fighting measures

Recommended extinguishing agent: Suitable extinguishing media: foam, carbon dioxide, dry
agent and water.

Product arising from burning: The substance is combustible and will burn if involved in a
fire, evolving noxious fumes (eg. oxides of carbon).
However, there is no experimental evidence to support the
anticipated combustion products.

Product determined by test: N

Protective equipment: Full protective clothing and self-contained breathing
apparatus must be worn.


Fight the fire from a safe distance or protected location.

Accidental release measures

Emergency measures in case of spillage: Evacuate personnel from the immediate vicinity.


Wear eye protection, impervious gloves, protective clothing
and footwear and a dust mask conforming to EN 149 FFP1,
along with an appropriate filter.


Avoid dust formation by damping down with water. Absorb
spillages of solutions with a suitable inert material (eg.
sand or soil). Carefully transfer the spillage to waste
containers, or use an approved sealed industrial vacuum
machine. Containers filled with waste material must be
labelled in the same way as the original 1,3-PPD containers.


Clean the spillage area with water.


Dispose of waste material in accordance with local
regulations by incineration or landfill, as specified in
Section A6.1.3.

Handling and storage

Handling: The substance should be stored, handled and used under
conditions of good industrial hygiene and in conformity with
any local regulations in order to avoid exposure by
ingestion, inhalation, skin and particularly eye contact.


Engineering controls are necessary to reduce exposure to the
substance.


When exposure cannot be prevented or adequately controlled
other than by the use of personal protective equipment, eye
protection (eg. goggles), impervious gloves, protective
clothing and footwear should be worn.


Furthermore, when respiratory protective equipment has to be
used, it must be capable of adequatedly controlling
exposure, and be suitable for the purpose. A dust mask and
filter conforming to EN149 FFP1 is recommended.

Storage: Store in sealed containers at room temperature.


Keep containers tightly closed when not in use.

Transport information

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Marine transport (IMDG)

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Air transport ICAO/IATA

Remarks
Transport: International Transport Codes: not available


Avoid crushing the containers. In the event of a spillage,
observe the warning labels on the container.
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Exposure controls / personal protection

Stability and reactivity

Danger other than fire: None known.

Chemical reaction with water: None which is hazardous.

Disposal considerations

Industry - Possibility of recovery/recycling: The substance will be used exclusively by industry and
confined to systems that are essentially open and batchwise
industrual operations, Handling of the substance will be by
trained operators, and it will be kept to a minimum.


Discharge to the environment will be minimal. Recovery from
minor spillages or accidental discharge is not economically
or technically feasible, and such waste material will be
disposed of by incineration or landfill in accordance with
Section A6.1.3. In principle, it may be possible to recover
larger spillages of uncontaminated material for subsequent
use.

Industry - Possibility of neutralisation: The Base Set tests have shown that the substance is an eye
irritant.


However, adequate protection will be worn during normal
handling and when dealing will spillages to ensure hazards
to health are minimised (see section A2.3.1).


The dust hazard will be minimised by damping down with
water.

Industry - Possibility of destruction: controlled discharge: Contaminated containers neat substance or spillages of
solutions mixed with inert material (eg. sand or soil) may
be disposed of by land fill at an authorised tip in
accordance with local regulations. (A:650).

Industry - Possibility of destruction - incineration: The substance can be disposed of by incineration, by burning
under controlled conditions at a licenced waste treatment
processor in accordance with local regulations. Stack gases
should be scrubbed, because noxious fumes (eg. carbon
oxides) could be formed. (A:661).

Industry - Possibility of destruction - water purification: The substance should not normally be discharged to the
sewage system or the aqueous environment.

Industry - Possibility of destruction - other: Not applicable.

Public at large - Possibility of recovery/recycling: Not applicable.

Public at large - Possibility of neutralisation: Not applicable.

Public at large - Possibility of destruction: controlled discharge: Not applicable.

Public at large - Possibility of destruction - incineration: Not applicable.

Public at large - Possibility of destruction - water purification: Not applicable.

Public at large - Possibility of destruction - others: Not applicable.