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Environmental fate & pathways

Biodegradation in water: screening tests

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Description of key information

No biodegradation expected.

Key value for chemical safety assessment

Biodegradation in water:
under test conditions no biodegradation observed

Additional information

The substance CAS 70942-01-7 was not tested for ready biodegradability, but four tests were performed to measure BOD5 and BOD/COD ratio. According to the Guidance on information requirements and Chemical Safety Assessment, Chapter R.7b: Endpoint specific guidance (Version 1.1, May 2008), information on the 5-day biochemical oxygen demand (BOD5) can be used for classification purposes only when no other measured degradability data are available; furthermore an estimation was performed on the substance with BIOWIN 4.10. The QSAR based screening criterion for identifying substances for persistency (P and vP) confirmed that the substance is expected to be persistent and this estimated behaviour is supported by the results obtained from the BOD5:COD ratio studies available.

Furthermore, a Zahn-Wellens/EMPA study (Novartis Services AG., 1997) was initiated on CAS 4193-55-9, the analogous substance with identical organic part and salification with sodium instead than sodium/potassium; the test was stopped because after 3 hours the substance demonstrated an adsorption of 66 %, and an 83.6 % after 24 hours.

One ready biodegradability and two inherent studies were performed on CAS 16470-24-9, the analogous substance, dihydroxyethyl derivative, tetrasulphonated. This analogous can be considered as a conservative representative, since the higher water solubility (650 mg/l vs 13.45 mg/l of CAS 70942-01-7) will lead to a better availability in the water compartment.

In the ready biodegradability study (Ciba Geigy 1992) a degradation of 1.2 % in 28 days was recorded, while the inherent studies (Ciba Geigy 1992 and 1997) indicated very low or no degradation at all.

As a conclusion the substance to under registration, CAS 70942-01-7, is expected to be neither readily nor inherently biodegradable.