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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
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EC number: 213-322-3 | CAS number: 937-14-4
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
General Advice: Immediate medical attention is required. Show this safety data sheet to the doctor in attendance.
Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required. Keep eye wide open while rinsing.
Skin Contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Call a physician immediately.
Ingestion: Do not induce vomiting. Immediate medical attention is required. Never give anything by mouth to an unconscious person. Drink plenty of water.
Inhalation: Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with a respiratory medical device. Call a physician or Poison Control Center immediately.
Protection of First-aiders: Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.
Most important symptoms and effects, both acute and delayed:
Causes burns by all exposure routes. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation.
Notes to Physician: Treat symptomatically.
Fire-fighting measures
Suitable Extinguishing Media: CO 2, dry chemical, dry sand, alcohol-resistant foam.
Special hazards arising from the substance or mixture:
The product causes burns of eyes, skin and mucous membranes. Organic peroxide. May undergo hazardous decomposition.
Hazardous Combustion Products:
Carbon monoxide (CO), Carbon dioxide (CO2), Hydrogen chloride gas, Thermal decomposition can lead to release of irritating
gases and vapors.
Advice for firefighters:
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.
Accidental release measures
Personal precautions, protective equipment and emergency procedures"
Use personal protective equipment. Evacuate personnel to safe areas. Avoid contact with skin, eyes and clothing.
Environmental precautions:
Should not be released into the environment. Do not allow material to contaminate ground water system.
Methods and material for containment and cleaning up:
Sweep up or vacuum up spillage and collect in suitable container for disposal. Avoid dust formation.
Handling and storage
Precautions for safe handling:
Use only under a chemical fume hood. Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Do not ingest. Do not breathe dust.
Conditions for safe storage, including any incompatibilities:
Keep containers tightly closed in a dry, cool and well-ventilated place. Corrosives area. Keep refrigerated. Do not store near combustible materials.
Specific end use(s):
Use in laboratories.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN3106
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN3106
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Marine transport (UN RTDG/IMDG)
- UN number:
- UN3106
Shipping information
- Proper shipping name and description:
- Organic peroxide type D, solid (Mixture)
- Chemical name:
- 3-Chloroperbenzoic acid
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN3106
Shipping information
- Proper shipping name and description:
- Organic peroxide type D, solid (Mixture)
- Chemical name:
- 3-Chloroperbenzoic acid
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Exposure controls / personal protection
Exposure limits:
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies
Biological limit values: This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies.
Monitoring methods:
BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents.
Predicted No Effect Concentration
(PNEC)
No information available.
Exposure controls:
Engineering Measures:
Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location.
Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or
equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source
Personal protective equipment:
Eye Protection Goggles (European standard - EN 166)
Hand Protection: Protective gloves
Skin and body protection: Long sleeved clothing Inspect gloves before use.
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves.
(Refer to manufacturer/supplier for information)
Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger
of cuts, abrasion. Remove gloves with care avoiding skin contamination.
Respiratory Protection: When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly
Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
Recommended Filter type: Particulates filter conforming to EN 143
Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Recommended half mask: Particle filtering: EN149:2001
When RPE is used a face piece Fit Test should be conductedHygiene Measures Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls: No information available.
Stability and reactivity
Substance is reactive.
Chemical stability:
Stable under normal conditions: Organic peroxide. Hazardous decomposition may occur.
Possibility of hazardous reactions:
Hazardous polymerization does not occur.
Hazardous Reactions: None under normal processing.
Conditions to avoid:
Incompatible products. Excess heat.
Incompatible materials:
Reducing agents. Combustible material. Strong bases.
Hazardous decomposition products:
Carbon monoxide (CO). Carbon dioxide (CO2). Hydrogen chloride gas. Thermal decomposition can lead to release of irritating gases and vapors.
Disposal considerations
Waste treatment methods:
Waste is classified as hazardous. Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.
Contaminated Packaging: Dispose of this container to hazardous or special waste collection point. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep product and empty container away from heat and sources of ignition.
European Waste Catalogue (EWC) According to the European Waste Catalogue, Waste Codes are not product specific, but
Application specific.
Other Information: Waste codes should be assigned by the user based on the application for which the product was used. Do not dispose of waste into sewer. Can be incinerated, when in compliance with local regulations. Do not empty into drains. Large amounts will affect pH and harm aquatic organisms.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.