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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

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Physical & Chemical properties

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Reference
Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
4 October 2010 to 21 December 2010
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
other: N4 (Modified method) Self Heating Substances
Deviations:
yes
Remarks:
The UN N4 test uses a large amount of test item. However, this test item is only available in very limited amounts therefore a modified procedure was employed
GLP compliance:
yes (incl. QA statement)
Relative self-ignition temperature:
388 °C

There were no signs of self-heating when held at 140 °C for 24 hours. When heated between 140 to 400 °C, self-heating occurred at 388 °C.

Conclusions:
Tetraammonium decachloro-mu-oxodiruthenate(4-) showed no signs of self-heating when held at 140 °C for 24 hours. When heated between 140 to 400 °C, self-heating occurred at 388 °C.
Executive summary:

Tremain and Atwal (2011) is a GLP compliant study following a modified UN N4 method and is suitable for use as the key study for this endpoint. Tetraammonium decachloro-mu-oxodiruthenate(4-) showed no signs of self-heating when held at 140 °C for 24 hours. When heated between 140 to 400 °C, self-heating occurred at 388 °C.

Description of key information

Tetraammonium decachloro-mu-oxodiruthenate(4-) showed no signs of self-heating when held at 140 °C for 24 hours. When heated between 140 to 400 °C, self-heating occurred at 388 °C.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
388 °C

Additional information

Tremain and Atwal (2011) is a GLP compliant study following a modified UN N4 method and is suitable for use as the key study for this endpoint. Tetraammonium decachloro-mu-oxodiruthenate(4-) showed no signs of self-heating when held at 140 °C for 24 hours. When heated between 140 to 400 °C, self-heating occurred at 388 °C.