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Diss Factsheets

Physical & Chemical properties

Flash point

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Administrative data

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Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: GLP status not known, guideline study, available as unpublished report, limitations in design and/or reporting but otherwise adequate for assessment.
Qualifier:
according to guideline
Guideline:
ISO No., other: DIN 51758
GLP compliance:
not specified
Type of method:
other: Not stated
Key result
Flash point:
>= 45 - <= 76 °C
Atm. press.:
other: Assumed pressure of 101.325 kPa
Remarks on result:
other: Value for RÜTGERS 02, RÜTGERS 04, RÜTGERS 05, RÜTGERS 06, RÜTGERS 07 and RÜTGERS 08.

Pressure not recorded assumed 101.3 kPa.

Conclusions:
The flash point of the substance CAS no. 68477-54-3 was determined to between 45°C and 76°C at an assumed pressure of 101.3 kPa.
Executive summary:

Data was received from the company reporting flash point. This data is considered reliable and suitable for use. The flash point of the substance CAS no. 68477-54-3 was determined to between 45°C and 76°C at an assumed pressure of 101.3 kPa.

Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Principles of method if other than guideline:
ASTM D 93(B)
GLP compliance:
not specified
Type of method:
other: Not specified
Key result
Flash point:
36.5 °C
Atm. press.:
101.325 kPa
Remarks on result:
other: Pressure assumed
Conclusions:
The flash point of CAS number 68477-54-3 is reported to be 36.5°C.
Executive summary:

The flash point of CAS number 68477-54-3 is reported to be 36.5°C. This data is considered acceptable for use as a key study.

Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
21.03.07 - 02.05.07
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: GLP unknown, Guideline Study, available as unpublished report, acceptable with restrictions
Qualifier:
according to guideline
Guideline:
ISO 13736:1997 (Petroleum products and other liquids - Determination of flash point - Abel closed cup method)
Version / remarks:
1997
GLP compliance:
not specified
Type of method:
closed cup
Key result
Flash point:
44.5 °C
Remarks on result:
other: Atm pressure not specified

flashpoint was determined as 44.5 Degs C

Conclusions:
The flashpoint for CAS Number 94733-07-0 is 44.5 degrees C.
Executive summary:

This is a guideline study considered adequate for assessment. The flashpoint for CAS Number 94733-07-0 is 44.5 degrees C.

Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
not reported
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: GLP unknown, guideline study, available as statement letter from registrant, acceptable with restrictions
Qualifier:
according to guideline
Guideline:
ISO No., other: 13736 (no other data)
Deviations:
not specified
GLP compliance:
not specified
Type of method:
other: not reported
Key result
Flash point:
57 °C
Atm. press.:
other: not specified
Remarks on result:
other: Atm pressure not specified

no further details

Conclusions:
The flashpoint of CAS No 101316-62-5 was determined as 57 Degs C.
Executive summary:

Information was provided by individual companies in the form of a letter stating the relevant information. The letter was submitted in company’s headed paper and signed by the individual responsible for the area of work. Given that the companies have practical expertise in handling the substance/stream this was deemed to be acceptable information.

The flashpoint of CAS No 101316-62-5 was determined as 57 Degrees C.

Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
not reported
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: GLP unknown, guideline study, available as statement letter from registrant, acceptable with restrictions
Qualifier:
according to guideline
Guideline:
ISO No., other: DIN 51758
Deviations:
not specified
Principles of method if other than guideline:
Not reported
GLP compliance:
not specified
Type of method:
other: not reported
Key result
Flash point:
66 °C
Atm. press.:
other: not specified
Remarks on result:
other: Atm pressure not specified

no further details

Conclusions:
The flashpoint of CAS No 101316-62-5 was determined as 66°C.
Executive summary:

Information was provided by individual companies in the form of a letter stating the relevant information. The letter was submitted in company’s headed paper and signed by the individual responsible for the area of work. Given that the companies have practical expertise in handling the substance/stream this was deemed to be acceptable information.

The flashpoint of CAS No 101316-62-5 was determined as 66°C.

Description of key information

Flash point data are available for 3 streams (5 studies) within this category ranging from 36.5 to 76°C.

Key value for chemical safety assessment

Flash point at 101 325 Pa:
46.4 °C

Additional information

The flash point values for streams in this category have been taken from proprietary data, study reports and certificates of analysis.

CAS# 94733-07-0: 44.5°C (BASF, 2007b),; CAS# 101316-62-5: 57 - 66°C (Rutgers, 2010b, c); CAS# 68477-54-3: 45-76°C (RÜTGERS 2010a, 2010b, 2010c, 2010d, 2010e, 2010f, 2010g, 2010h); CAS# 68477-54-3: 36.5°C (SIBUR, 2009).

These data will be read across to all category members.

The mean flash point value is 46.4°C and this has been used to complete the ‘key value for chemical safety assessment’.