Allylamine

Guidance on Safe Use

First-aid measures

1. Description of first aid measures

First-aid measures general : Call a physician immediately. Remove immediately contaminated clothing. Remove and isolate contaminated clothing and shoes. Remove breathing protection only after removing contaminated clothing. Artificial respiration in case of irregular breathing or respiratory arrest.

First-aid measures after inhalation : Assure fresh air breathing. Keep victim warm and rested. Artificial respiration and/or oxygen if necessary. If symptoms persist, call a physician. Get immediate medical advice/attention.

First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Get immediate medical advice/attention.

First-aid measures after eye contact : Rinse immediately and thoroughly, pulling the eyelids well away from the eye (15 minutes minimum). Call a physician immediately.

First-aid measures after ingestion : Call a physician immediately. Do not induce vomiting.

2. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

Fire-fighting measures

1. Extinguishing media

Suitable extinguishing media : Water spray. Dry powder. Carbon dioxide. Alcohol resistant foam.

2. Special hazards arising from the substance or mixture

Fire hazard : Highly flammable liquid and vapour.

Hazardous decomposition products in case of fire: Carbon oxides (CO, CO2). Nitrogen oxides.

3. Advice for firefighters

Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.

Accidental release measures

1. Personal precautions, protective equipment and emergency procedures

1.1. For non-emergency personnel

Emergency procedures : Wear personal protective equipment. Evacuate area. Avoid ignition sources. No open flames, no sparks, and no smoking.

1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment.

2. Environmental precautions

Do not allow into drains or water courses.

3. Methods and material for containment and cleaning up

For containment : Provide adequate ventilation.

Methods for cleaning up : Collect liquids by means of a sluggish absorbing material (sand, neutralizing of acid, sawdust) and evacuate as a special waste. Keep in bowls adapted and closed for the elimination.

Other information : Dispose of materials or solid residues at an authorized site.

Handling and storage

1. Precautions for safe handling

Precautions for safe handling : Handle under inert gas. Keep the container hermetically sealed. Ensure good ventilation of the work station. Keep away from sources of ignition - No smoking. Use explosion-proof equipment. Take precautionary measures against static discharge.

Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.

2. Conditions for safe storage, including any incompatibilities

Technical measures : Ground/bond container and receiving equipment.

Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up.

Store away from oxidation agents. Store in dry, well-ventilated area. Keep under inert gas.

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediate. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management system is available at each site. Written confirmation of application of Strictly Controlled Conditions has been received from every Downstream user of the intermediate.”

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

2334

Shipping

Labels:

6.1
+3

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

2334

Shipping

Labels:

6.1
+3

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

2334

Shipping information

Proper shipping name and description:

ALLYLAMINE (Allylamine)
UN 2334 ALLYLAMINE (Allylamine), 6.1 (3), I, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS (-29°C c.c.)

Chemical name:

ALLYLAMINE

Labels:

6.1
+3

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

Not regulated

Shipping information

Proper shipping name and description:

Not regulated

Chemical name:

ALLYLAMINE

Labels:

Not regulated

Remarks

SpecialProvisions

Exposure controls / personal protection

Exposure controls

Appropriate engineering controls:

Ensure good ventilation of the work station. Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute. Handle in accordance with good industrial hygiene and safety practice. Always wash your hands immediately after handling this product, and once again before leaving the workplace. Avoid contact with skin, eyes and clothing. Remove soiled clothing promptly. Keep away from food, drink and animal feeding stuffs.

Hand protection:

Manipulate with gloves. Gloves have to be controlled before the use. Use a technique of withdrawal of gloves suited to avoid that the skin contacts

the product (i.e. without touching the outside surface of the glove). Throw gloves contaminated after the use according to the current laws and to the

good practices of laboratory. Wash and dry hands. The selected gloves have to satisfy the specifications of the EU Directive 89 / 686 / EEC and in

the standard IN 374 which derives from it.

Eye protection:

Safety glasses

Skin and body protection:

Wear suitable protective clothing

Respiratory protection:

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (or equivalent) and full protective gear. Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Environmental exposure controls:

Avoid release to the environment.

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediate. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management system is available at each site. Written confirmation of application of Strictly Controlled Conditions has been received from every Downstream user of the intermediate.

Stability and reactivity

Chemical stability

Stable under normal conditions.

Possibility of hazardous reactions

Reacts violently with (strong) oxidizers.

Incompatible materials

Oxidizing agent. air.

Hazardous decomposition products

Nitrous gases. Carbon oxides (CO, CO2).

Disposal considerations

Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions. Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. Assure discharge

complies with applicable regulations. Must follow special treatment according to local regulation.

Additional information : Flammable vapours may accumulate in the container.