Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General advice: If symptoms persist, call a physician. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing.

- Inhalation: Remove to fresh air. Call a physician. If breathing is irregular or stopped, administer artificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation.
- Skin Contact: Consult a physician if necessary. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Wash off immediately with soap and plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing before reuse.
- Eye contact: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician.
- Ingestion: Rinse mouth. Drink plenty of water. If symptoms persist, call a physician. Do NOT induce vomiting.

- Self-protection of the first aider: Use personal protective equipment as required. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.

- Most important symptoms and effects, both acute and delayed: None known.

- Indication of any immediate medical attention and special treatment needed
Note to physicians: Treat symptomatically.

Fire-fighting measures

- Suitable extinguishing media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
- Unsuitable extinguishing media: Do not use a solid water stream as it may scatter and spread fire

- Special hazards arising from the substance or mixture: Runoff may pollute waterways.

- Hazardous combustion products: Carbon oxides. Hazardous metal fumes and oxides. Hydrocarbons. Oxides of sulfur.

- Advice for firefighters: Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.

Accidental release measures

> Personal precautions, protective equipment and emergency procedures
- Personal precautions: Use personal protective equipment as required.
- For emergency responders: Use personal protection recommended in 'Exposure Controls/ Personal Protection' section

> Environmental precautions
Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. The product is insoluble and floats on water. Prevent further leakage or spillage if safe to do so. Do not allow into any sewer, on the ground or into any body of water. Prevent product from entering drains.

> Methods and material for containment and cleaning up
- Methods for containment: Prevent further leakage or spillage if safe to do so.
- Methods for cleaning up: Cover liquid spill with sand, earth or other non-combustible absorbent material. Cover powder spill with plastic sheet or tarp to minimize spreading. Pick up and transfer to properly labelled containers. Soak up with inert absorbent material.

Handling and storage

> Precautions for safe handling
- Advice on safe handling: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wash contaminated clothing before reuse. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product.
- General Hygiene Considerations: Handle in accordance with good industrial hygiene and safety practice.

> Conditions for safe storage, including any incompatibilities
- Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. Protect from direct sunlight.

Transport information

Land transport (ADR/RID)

UN number:
UN2788
Proper shipping name and description:
ORGANOTIN COMPOUND, LIQUID, N.O.S. (METHYLTIN TRIS (2-ETHYLHEXYL MERCAPTOACETATE))
Chemical name:
2-ethylhexyl 10-ethyl-4-[[2-[(2-ethylhexyl)oxy]-2-oxoethyl]thio]-4-methyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate
Language:
English
Class:
6.1
Classification code:
T3
Packaging group:
III
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN2788
Proper shipping name and description:
ORGANOTIN COMPOUND, LIQUID, N.O.S. (METHYLTIN TRIS (2-ETHYLHEXYL MERCAPTOACETATE))
Chemical name:
2-ethylhexyl 10-ethyl-4-[[2-[(2-ethylhexyl)oxy]-2-oxoethyl]thio]-4-methyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate
Language:
English
Class:
6.1
Classification code:
T3
Packaging group:
III
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN2788
Proper shipping name and description:
ORGANOTIN COMPOUND, LIQUID, N.O.S. (METHYLTIN TRIS (2-ETHYLHEXYL MERCAPTOACETATE))
Chemical name:
2-ethylhexyl 10-ethyl-4-[[2-[(2-ethylhexyl)oxy]-2-oxoethyl]thio]-4-methyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate
Class:
6.1
Packaging group:
III
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN2788
Proper shipping name and description:
ORGANOTIN COMPOUND, LIQUID, N.O.S. (METHYLTIN TRIS (2-ETHYLHEXYL MERCAPTOACETATE))
Chemical name:
2-ethylhexyl 10-ethyl-4-[[2-[(2-ethylhexyl)oxy]-2-oxoethyl]thio]-4-methyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate
Class:
6.1
Packaging group:
III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

> Exposure controls
- Engineering Controls: Ensure adequate ventilation, especially in confined areas. Showers. Eyewash stations.

> Personal protective equipment
- Eye/face protection: Tight sealing safety goggles. Eye protection worn must be compatible with respiratory protection system employed.
- Hand Protection: For operations where prolonged or repeated skin contact may occur, impervious gloves should be worn. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves.
- Skin and body protection: Suitable protective clothing. Gloves made of plastic or rubber.
- Respiratory protection: Use certified respiratory protection equipment meeting EU requirements(89/656/EEC, 89/686/EEC ), or equivalent, when respiratory risks cannot be avoided or sufficiently limited by technical means of collective protection or by measures, methods or procedures of work organization.

> Environmental exposure controls: Do not allow into any sewer, on the ground or into any body of water.


Exposure limits are listed below, if they exist.

Methyltin tris(2-ethylhexyl thioglycolate)
TWA: 0.1 mg/m³ (skin) - UK, Denmark
TWA: 0.1 mg/m³; STEL: 0.2 mg/m³ - France, Ireland
TWA: 0.2 mg/m³; STEL 0.1 mg/m³ - Spain, Portugal, Austria, Switzerland
TWA: 0.1 mg/m³; STEL 0.3 mg/m³ - Finland, Norway

Stability and reactivity

> Reactivity: No data available.

> Chemical stability: Stable under normal conditions.

> Explosion data
- Sensitivity to Mechanical Impact: None.
- Sensitivity to Static Discharge: None.

> Possibility of hazardous reactions
- Hazardous polymerization: Hazardous polymerization does not occur.
- Possibility of Hazardous Reactions: None under normal processing.

> Conditions to avoid
Extremes of temperature and direct sunlight. Exposure to air or moisture over prolonged periods. Keep out of reach of children.

> Incompatible materials
Acids. Strong oxidizing agents. Incompatible with strong acids and bases. Incompatible with oxidizing agents.

> Hazardous decomposition products
None under normal use conditions.

Disposal considerations

- Waste from Residues / Unused Products: Disposal should be in accordance with applicable regional, national and local laws and= regulations.

- Contaminated packaging: Do not reuse container. Disposal should be in accordance with applicable regional, national and local laws and regulations.

- Waste codes / waste designations according to EWC / AVV: Waste codes should be assigned by the user based on the application for which the product was used.

- Other Information Waste codes should be assigned by the user based on the application for which the product was used.