Registration Dossier
Registration Dossier
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EC number: 213-313-4 | CAS number: 936-49-2
Guidance on Safe Use
Administrative data
First-aid measures
INHALATION
Move the exposed person to fresh air at once. Get medical attention.
INGESTION
Harmful if swallowed. Wash out mouth with water, provided person is conscious. Get medical attention immediately.
SKIN CONTACT
Irritating to skin. Remove contaminated clothing and wash skin with soap and plenty of running water. Get medical attention.
EYE CONTACT
Risk of serious damage to eyes. Rinse immediately eye with plenty of low pressure water for at least 15 minutes.
Remove any contact lenses. Get medical attention.
Fire-fighting measures
EXTINGUISHING MEDIA
Flashpoint 151 °C (open cup)
To extinguish fire use water spray, dry powder, carbon dioxide, or foam.
SPECIAL FIRE FIGHTING PROCEDURES
Prevent run-off water from entering the sewer system.
UNUSUAL FIRE & EXPLOSION HAZARDS
Dust may form explosive mixture with air.
SPECIFIC HAZARDS
By fire toxic gases may be formed (Cox, NOx).
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing.
Accidental release measures
PERSONAL PRECAUTIONS
See section on exposure controls/personal protection
ENVIRONMENTAL PRECAUTIONS
Take precautionary measures against discharges into the environment.
SPILL CLEAN UP METHODS
Collect spilled material without creating dust, then place into a suitable closed container for disposal as chemical waste.
Handling and storage
USAGE PRECAUTIONS
Concentrated dust may present an explosion hazard.
Avoid contact with eyes or skin.
Wash thoroughly after handling and before eating, drinking or smoking.
STORAGE PRECAUTIONS
To protect product quality, store in sealed container in a cool place and out of direct sunlight.
Protect against static charge and keep away from source of ignition. Prevent dust formation.
Transport information
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SpecialProvisionsopen allclose all
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
EXPOSURE LIMITS
None listed.
USE LIMITS
Only to be handled in an industrial environment as
• industrial feedstock for further chemical synthesis or
• as powder coating additive (as such or in a mixture)
PNECs:
aqua-freshwater: 0.72 E-3 mg/L
aqua-marine water: 0.72 E-4 mg/L
aqua-intermittent: 0.72 E-2 mg/L
sewage treatment plant: 14 mg/L
sediment-freshwater: 0.108 mg/kg dw
sediment-marine water: 0.0108 mg/kg dw
soil: 10 mg/kg dw
DNELs:
The main derived long-term DNELs for systemic effects are:
Workers General population
Oral not relevant 0.408 mg/kg bw/day
Dermal 0.816 mg/kg bw/day 0.408 mg/kg bw/day
Inhalation 0.72 mg/m3 0.1774 mg/m3
The CHESAR Tool version2.3.0, exposure model for this substance shows for
• indoor industrial activities
• with an advanced occupational health and safety system
• taking more than 4 hours/day
• with local exhaust ventilation (LEV) present (and running)
• provided workers wear masks with at least 90% respiratory protection
• and gloves with at least 95% dermal protection
the following long term systemic exposures:
Inhalation dermal RCR RCR RCR
mg/m3 mg/kg/day inhalation dermal total
PROC1 0.0007 0.002 < 0.01 < 0.01 < 0.01
Use in closed process, no likelihood of exposure
PROC2 0.00007 0.007 < 0.01 <0.01 <0.01
Use in closed, continuous process with occasional controlled exposure
PROC3 0.0007 0.003 < 0.01 <0.01 <0.01
Use in closed batch process (synthesis or formulation)
PROC4 0.003 0.034 0.005 0.042 0.047
Use in batch and other process (synthesis) where opportunity for exposure arises
PROC5 0.003 0.069 0.005 0.084 0.089
Mixing or blending in batch processes (multistage and/or significant contact)
PROC7 0.003 0.107 0.005 0.131 0.136
Industrial spraying
PROC8a 0.003 0.069 0.005 0.084 0.089
Transfer of chemicals from/to vessels/ large containers at non dedicated facilities
PROC8b 0.00035 0.034 < 0.01 0.042 0.042
Transfer of chemicals from/to vessels/large containers at dedicated facilities
PROC9 0.0007 0.034 < 0.01 0.042 0.042
Transfer of chemicals into small containers (dedicated filling line)
PROC15 0.0007 0.002 < 0.01 < 0.01 < 0.01
Use as laboratory reagent
Note:
• The outcome of ECETOC TRAM v3 (10 April 2012) is identical to CHESAR v2.3.0
• Good general ventilation is assumed in all cases (3-5 air exchanges per hour)
• Dustiness of the substance was set at “low”
• The applied RMMs/OCs will also control the risks relating to possible skin & eye irritation and skin sensitisation
• LEV is considered for both inhalation and dermal exposures and its efficiencies are as follows:
o For PROC1 LEV is not an exposure modifier
o For PROC7 and PROC8b LEV reduces both inhalation and dermal exposure with 95%
o For all other PROCs LEV reduces both inhalation and dermal exposure with 90%
The CHESAR Tool version2.3.0, exposure model for this substance shows for
• indoor professional activities
• with a basic occupational health and safety system
• taking less than 8 hour/day and with max 5% substance in the mixture
• with local exhaust ventilation (LEV) present (and running)
• provided workers wear masks with at least 90% respiratory protection
• and gloves with at least 90% dermal protection
the following long term systemic exposures:
Inhalation dermal RCR RCR RCR
mg/m3 mg/kg/day inhalation dermal total
PROC11 0.004 0.429 0.006 0.525 0.531
Non-industrial spraying
Note:
• The outcome of ECETOC TRAM v3 (10 April 2012) is identical to CHESAR v2.3.0
• Basic general ventilation is assumed in all cases (1-3 air exchanges per hour)
• Dustiness of the substance was set at “low”
• The concentration of the substance in the powder coating mixture is 1-5%
• The applied RMMs/OCs will also control the risks relating to possible skin & eye irritation and skin sensitisation
• LEV is considered for both inhalation and dermal exposures and its efficiencies are as follows:
o For PROC11 LEV reduces both inhalation and dermal exposure with 80%
PROTECTIVE EQUIPMENT
Protective gloves, safety goggles, breathing apparatus and protective clothing. Avoid any source of ignition and/or static charge.
RESPIRATORY EQUIPMENT
Breathing apparatus: Wear positive pressure self-contained breathing apparatus classified under EN137 : 2006 with at least 90% respiratory protection..
HAND PROTECTION
Protective gloves: Use chemical resistant gloves classified under Standard EN374, class 6 (breakthrough time > 480 minutes) and give operators specific training. Discard gloves after each working day.
EYE PROTECTION
Wear approved safety goggles.
HYGIENE MEASURES
Wash at the end of each work shift and before eating, drinking, smoking or using the toilet.
SKIN PROTECTION
Wear protective clothing.
Stability and reactivity
STABILITY
Stable under normal temperature conditions and recommended use.
MATERIALS TO AVOID
Strong oxidising agents
HAZARDOUS DECOMPOSITION PRODUCTS
By fire toxic gases (COx, NOx) may be formed
Disposal considerations
GENERAL INFORMATION
Place into a suitable closed container for disposal as chemical waste.
DISPOSAL METHODS
Dispose of in accordance with local and national regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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