Registration Dossier
Registration Dossier
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EC number: 609-256-3 | CAS number: 365400-11-9
Guidance on Safe Use
Administrative data
First-aid measures
General advice
Move out of dangerous area. Remove contaminated clothing immediately and dispose of safely. Place and transport victim in stable position (lying sideways).
Inhalation
Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately.
Skin contact
Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. If symptoms persist, call a physician.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists.
Ingestion
Do NOT induce vomiting. Call a physician or poison control center immediately. Rinse mouth.
Most important symptoms and effects, both acute and delayed
Symptoms
No symptoms known or expected.
Indication of any immediate medical attention and special treatment needed
Treatment
Treat symptomatically. There is no specific antidote. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable.
Fire-fighting measures
Extinguishing media
Suitable: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable: High volume water jet
Special hazards arising from the substance or mixture
In the event of fire the following may be released: Carbon monoxide (CO), Hydrogen fluoride, Nitrogen oxides (NOx), Sulphur oxides, Hydrogen cyanide (hydrocyanic acid), Accumulation of fine dust may entail the risk of a dust explosion in the presence of air.
Advice for firefighters
Special protective equipment for firefighters: In the event of fire and/or explosion do not breathe fumes. In the event of fire, wear self-contained breathing apparatus.
Further information: Fight fire from upwind position. Keep out of smoke. Cool closed containers exposed to fire with water spray. Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Precautions: Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment. Avoid dust formation. Remove all sources of ignition.
Environmental precautions: Do not allow to get into surface water, drains and ground water.
Methods and materials for containment and cleaning up
Methods for cleaning up: Avoid dust formation and electrical charging (sparking) because dust explosion might occur. Use mechanical handling equipment. Clean contaminated floors and objects thoroughly, observing environmental regulations. Keep in suitable, closed containers for disposal.
Handling and storage
Precautions for safe handling
Advice on safe handling: Traces of hydrogen cyanide vapour can collect in the empty space of closed containers. Avoid dust formation. Use only in area provided with appropriate exhaust ventilation. Handle and open container in a manner as to prevent spillage.
Advice on protection against fire and explosion: Take measures to prevent the build up of electrostatic charge. Keep away from heat and sources of ignition. Dust may form explosive mixture in air.
Hygiene measures: Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands before breaks and immediately after handling the product. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt).
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers: Keep containers tightly closed in a dry, cool and well-ventilated place. Store in original container. Store in a place accessible by authorized persons only. Keep away from direct sunlight.
Advice on common storage: Keep away from food, drink and animal feedingstuffs.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (PYRASULFOTOLE)
- Chemical name:
- PYRASULFOTOLE
- Language:
- English
- Class or division:
- Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
- Packing group:
- Packing group III: Substances presenting low danger
- Labels:
- Packaging: 9, E1
Bulk: 9, E1
Haz ID: 90
EAC 2Z
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (PYRASULFOTOLE)
- Chemical name:
- PYRASULFOTOLE
- Language:
- English
- Class or division:
- Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
- Packing group:
- Packing group III: Substances presenting low danger
- Labels:
- Packaging: 9, E1
Bulk: 9, E1
Haz ID: 90
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (PYRASULFOTOLE)
- Chemical name:
- PYRASULFOTOLE
- Language:
- English
- Class or division:
- Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
- Packing group:
- Packing group III: Substances presenting low danger
- EmS code:
- F-A
- S-F
- Labels:
- Packaging: 9, P
Bulk: 9, P - Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (PYRASULFOTOLE)
- Chemical name:
- PYRASULFOTOLE
- Language:
- English
- Class or division:
- Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
- Packing group:
- Packing group III: Substances presenting low danger
- Labels:
- Packaging: 9, E1
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters
| Components | CAS-No. | Control parameters | Basis |
Pyrasulfotole | 365400-11-9 | 0,3 mg/m3 (TWA) | OES BCS* |
*OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure Standard"
Exposure controls
Respiratory protection: Wear respirator with a particle filter mask (protection factor 4) conforming to European norm EN149FFP1 or equivalent.
Hand protection: Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness of 0,4 mm, minimum rate of permeability 480 min). Wash when contaminated and dispose of when contaminated inside, when perforated or when contamination on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet.
Eye protection: Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).
Skin and body protection: Wear standard coveralls and Category 3 Type 5 suit. Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.
Stability and reactivity
Reactivity: Stable under normal conditions.
Chemical stability: Stable under normal conditions.
Possibility of hazardous reactions: Incapable of deflagration Stable under normal conditions. No hazardous reactions when stored and handled according to prescribed instructions.
Hazardous decomposition products: No decomposition products expected under normal conditions of use.
Disposal considerations
Waste treatment methods
Product: In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant.
Contaminated packaging: Not completely emptied packagings should be disposed of as hazardous waste.
Waste key for the unused product: 02 01 08* agrochemical waste containing hazardous substances
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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