Registration Dossier
Registration Dossier
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EC number: 278-817-9 | CAS number: 78014-16-1
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Pay attention to self-protection.
Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim warm, in a stabilizedposition and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation
Potential for exposure by inhalation if aerosols or mists are generated.
Move victims into fresh air.
With labored breathing: Provide with oxygen. Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact
Wash off affected area immediately with plenty of water for at least 15 minutes.
If symptoms persist, consult a physician for treatment.
Eye contact
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
When dealing with caustic substances, notify emergency physician immediately (key words: burns in eye).
Ingestion
Rinse mouth.
Immediately give large quantities of water to drink.
Obtain medical attention.
When dealing with caustic substances, notify emergency physician immediately.
Most important symptoms and effects, both acute and delayed
Symptoms
Irritation of skin and mucous membranes
Causes burns.
daze,
Headache, vertigo, somnolence (sleepiness), nausea.
Health injuries may be delayed.
Hazards
Srongly irritating to corrosive.Harmful in contact with skin and if swallowed. Vapours may cause drowsiness and dizziness.
Indication of any immediate medical attention and special treatment needed
The initial focus is only on the local action, characterized by quickly progressing deep tissue damage.
In the eye, caustic/ irritating and harmful liquids cause, depending on the intensity of exposure, various levels of irritation, destruction, and ablation of the epithelium of the conjunctiva and cornea, corneal clouding, edema and ulcerations.
Danger! Possible loss of eyesight!
Superficial irritations and damage up to ulcerations and scarring develop on the skin.
After accidental absorption in the body, the pathology and clinical findings are dependent on the kinetics of the substance (quantity of absorbed substance, the absorption time, and the effectiveness of early elimination measures (first aid)/ excretion - metabolism).
A specific action of the substance is unknown.
In case of substances with high water solubility, irritations up to formation of necrosis in the upper respiratory tract may result after inhalation of caustic/ irritating aerosols and mists.
The initial focus is on the local action: signs of irritation of the respiratory tract such as coughing, burning behind the sternum, tears, burning in the eyes or nose.
There is a risk of pulmonary edema!
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: water spray, foam, dry powder
Unsuitable extinguishing media: high volume water jet
Special hazards arising from the substance or mixture
Hazardous fumes in fires, specific to the product:
nitrogen oxides (NOx)
Carbon monoxide
Advice for firefighters
Water for fire fighting must not be introduced in the sewer system, subsoil, or surface waters. Assure that there are sufficient fire water retaining facilities Contaminated fire fighting water must be disposed of in conformity with the regulations of the local authorities.
Fire residues should be disposed of in accordance with the regulations.
In case of fire use self-contained breathing apparatus if necessary.
Wear suitable protective clothing.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes.
Wear personal protective equipment.
Environmental precautions
Prevent product from entering drains.
Do not allow to reach the sewage system, the ground or natural water bodies.
Methods and material for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Fill into marked, sealable containers.
Reference to other sections
Wear personal protective equipment; see section 8.
Handling and storage
Precautions for safe handling
If the product is thermally treated, provide for a vapour exhaust device.
Avoid contact with skin and eyes.
Wear personal protective equipment
Conditions for safe storage, including any incompatibilities
Advice on protection against fire and explosion
Vapours may form explosive mixtures with air.
Take precautionary measures against static discharges.
Keep away from sources of ignition - No smoking.
Storage
Keep containers tightly closed in a cool, well-ventilated place.
German storage class: 8L - Corrosive Liquids
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2735
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 2735
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Marine transport (UN RTDG/IMDG)
- UN number:
- 2735
Shipping information
- Proper shipping name and description:
- AMINES, LIQUID, CORROSIVE, N.O.S. (Triacetonetriamine)
- Chemical name:
- Triacetonetriamine
- Labels:
- 8
- Marine pollutant
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2735
Shipping information
- Proper shipping name and description:
- Amines, liquid, corrosive, n.o.s. (Triacetonetriamine)
- Chemical name:
- Triacetonetriamine
- Labels:
- 8
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Exposure controls / personal protection
Engineering measures
If possible, use material transfer/filling, metering and blending plants that are closed.
Personal protective equipment
Respiratory protection
Use suitable respiratory protection where aerosols/vapours are generated.
use respiratory equipment with suitable filter or wear a self contained respiratory apparatus
Respirator with ABEK combination filter
Note time limit for wearing respiratory protective equipment.
Hand protection
Applies to handling for brief periods or of small amounts
Glove material Nitrile, for example, Dermatril P 743, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness 0,2 mm
Method DIN EN 374
Applies to handling for longer periods or of large amounts
Glove material Nitrile/Chloroprene, for example, Nitopren 717, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness 0,65 mm
Method DIN EN 374
Selection of protective gloves to meet the requirements of specific workplaces.
Suitability for specific workplaces should be clarified with protective glove manufacturers.
The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials.
Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined according to
EN 374 due to the many different influential factors involved (e.g. temperature).
The data about break through time/strength of material is not valid for undissolved solids/dust.
Eye protection
close-fitting protective goggles (e.g. closed goggles)
Skin and body protection
suitable protective clothing
Use disposable clothing if appropriate.
Hygiene measures
Avoid contact with skin and eyes.
Wash off immediately in the event of contact with the skin (rinsing agent: glycol polyethylene 400), rinse off afterwards with copious amounts of water.
Remove immediately all contaminated clothing.
Do not eat, drink, smoke, or sniff while at work. Wash your hands and/or face before breaks and before termination of work.
Protective measures
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
Stability and reactivity
Hazardous decomposition products
NH3
Disposal considerations
Waste treatment methods
With respect to local regulations, e.g. dispose of to suitable waste incineration plant.
No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer.
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Waste Key Number
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
