Registration Dossier
Registration Dossier
Data platform availability banner - registered substances factsheets
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 240-969-9 | CAS number: 16919-27-0
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
- General advice: First aider needs to protect himself. Take off all contaminated clothing immediately. Victim to lie down in the recovery position, cover and keep him warm. Call a physician immediately.
- Inhalation : Move to fresh air. Call a physician immediately.
- Skin contact : Take off all contaminated clothing immediately. Wash off immediately with plenty of water. First treatment with calcium gluconate paste. Call a physician immediately.
- Eye contact : Protect unharmed eye. Rinse thoroughly with plenty of water, also under the eyelids. Call a physician immediately.
- Ingestion : A person suspected to have swallowed the substance who is conscious should be given water to drink. Take to a doctor immediately together with this card
Fire-fighting measures
- Suitable extinguishing media: Water spray, Foam, Carbon dioxide (CO2), Dry powder
- Specific hazards during fire fighting: Exposure to decomposition products may be a hazard to health. Fire may cause evolution of: Hydrogen fluoride
- Special protective equipment for fire-fighters: Wear self-contained breathing apparatus and protective suit.
- Further information : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. The product itself does not burn. Standard procedure for chemical fires.
Accidental release measures
- Personal precautions: Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid dust formation.
- Environmental precautions : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Clean contaminated floors and objects thoroughly while observing environmental regulations. Try to prevent the material from entering drains or water courses. Prevent further leakage or spillage if safe to do so.
- Methods for cleaning up : Use mechanical handling equipment. Avoid dust formation. Pick for disposal in tightly closed containers. Clean contaminated surface thoroughly.
Handling and storage
Handling
- Advice on safe handling: Exhaust ventilation at the object is necessary. Vent waste air to atmosphere only through suitable separators. Avoid formation of respirable particles.
- Advice on protection against fire and explosion: No special precautions required.
- Hygiene measures : Take off all contaminated clothing immediately. Wash hands before breaks and immediately after handling the product. Regular cleaning of equipment, work area and clothing. Keep working clothes separately. Separate rooms are required for washing, showering and changing clothes.
Storage
- Further information on storage conditions: Keep containers tightly closed in a dry, cool and well-ventilated place.
- Advice on common storage : Do not store together with: Acids
Transport information
Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Remarksopen allclose all
Shippingopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
- Occupational exposure limits:
IOELV: 2.5 mg/m³ based on fluoride
Adopted as a DNEL under REACH. Corresponds to 5.2 mg K2TiF6/m³.
- Occupational exposure controls: Do not breathe dust. The Personal Protective Equipment must be in accordance with EN standards:respirator EN 136, 140, 149; safety glasses EN 166; protective suit: EN 340, 463, 468, 943-1, 943-2; gloves EN 374, safety shoes EN-ISO 20345. Always have on hand a first-aid kit, together with proper instructions.
- Environmental exposure controls: Handle in accordance with local environmental regulations and good industrial practices.
- Engineering measures: Local exhaust
- Personal protective equipment: Respiratory protection : Full mask, P3, Remarks: In the case of dust or aerosol formation use respirator with an approved filter.
- Hand protection: Glove material: Natural Latex, Break through time: > 480 min, Glove thickness: 0,6 mm, Lapren®706, Remarks: Supplementary note: The specifications are based on information and tests from similar substances by analogy. Due to varying conditions ( e.g.temperature or other strains) it must be considered that the usage of a chemical protective glove in practice may be much shorter than the permeation time determined in accordance with EN 374. Since actual conditions of practical use often deviate from standardised conditions according EN 374 the glove manufacturer reccomends to use the chemical protective glove in practice not longer than 50% of the recomended permeation time. Manufacturer´s directions for use should be observed because of great diversity of types. Suitable gloves tested according EN 374 are supplied e.g. from KCL GmbH, D-36124 Eichenzell, Vertrieb@kcl.de.
- Eye protection: see respiratory protection
- Skin and body protection: impervious clothing
Stability and reactivity
- Conditions to avoid: Heating will cause pressure rise with risk of bursting
- Materials to avoid: Contact with strong acids liberates hydrogen fluoride.
- Hazardous decomposition products: Hydrogen fluoride
- Stability and reactivity : No decomposition if used as directed., Fire or intense heat may cause violent rupture of packages.
Disposal considerations
- Product: Dispose according to legal requirements.
- Packaging: Legal requirements are to be considered in regard of reuse or disposal of used packaging materials
- Further information: Provisions relating to waste: EC Directive 2006/12/EC; 91/689/EEC Regulation No. 1013/2006
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.