Registration Dossier
Registration Dossier
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EC number: 204-589-7 | CAS number: 122-99-6
Guidance on Safe Use
Administrative data
First-aid measures
General advice:
First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). Immediately remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Note to physician:
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. If hemolysis is suspected, monitor hemoglobin, hematocrit, plasma free hemoglobin, and urinalysis. Whole blood or packed RBC transfusion may be required in severe cases. Alkalinization of urine with bicarbonate may prevent renal damage. Maintain adequate ventilation and oxygenation of the patient.
Fire-fighting measures
Suitable extinguishing media:
water spray, dry powder, foam
Special hazards arising from the substance or mixture:
Endangering substances: harmful vapours, carbon oxides
Advice: Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire.
Advice for fire-fighters:
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations.
Accidental release measures
High risk of slipping due to leakage/spillage of product.
Personal precautions, protective equipment and emergency procedures:
Use personal protective clothing.
Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up:
For large amounts: Dike spillage. Pump off product.
For residues: Pick up with suitable absorbent material.
Dispose of absorbed material in accordance with regulations.
Handling and storage
Handling
Precautions for safe handling:
Prevent contact with air/oxygen (formation of peroxide).
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Conditions for safe storage, including any incompatibilities:
Suitable materials for containers: Stove-lacquer RDL 50, glass, High density polyethylene (HDPE), Low density polyethylene (LDPE), tinned carbon steel (Tinplate), Stainless steel 1.4301 (V2), Stainless steel 1.4306 (V2A), Stainless steel 1.4361, Stainless steel 1.4401, Stainless steel 1.4541, Stainless steel 1.4571, Stainless steel 1.4439
Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated place. Protect from atmospheric humidity. Protect against moisture. Prevent entry of air/oxygen. Formation of peroxides.
The product is not damaged by low temperatures or by frost.
Protect from temperatures above:100 °C
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not classified as hazardous
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- Not classified as hazardous
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Marine transport (UN RTDG/IMDG)
- UN number:
- Not classified as hazardous
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Not classified as hazardous
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Exposure controls / personal protection
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Hand protection:
Chemical resistant protective gloves (EN ISO 374-1)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN ISO 374-1):
fluoroelastomer (FKM) - 0.7 mm coating thickness
Polyethylene-Laminate (PE laminate) - ca. 0.1 mm coating thickness
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN ISO 374-1)
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
Wearing of closed work clothing is recommended. No eating, drinking, smoking or tobacco use at the place of work. Handle in accordance with good industrial hygiene and safety practice.
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Stability and reactivity
Reactivity:
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals: | Corrosive effects to metal are not anticipated. | |
Formation of flammable gases: | Remarks: | Forms no flammable gases in the presence of water. |
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Peroxides: | The product/the substance has a tendency towards the formation of peroxide. |
Possibility of hazardous reactions
May form explosive peroxides when exposed to air. Substance/product can form explosive mixture with air.
The product is stable if stored and handled as prescribed/indicated.
Conditions to avoid:
Avoid heat. Avoid contact with air. Avoid humidity.
Substances to avoid:
strong oxidizing agents
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
Disposal considerations
Must be disposed of or incinerated in accordance with local regulations.
Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
