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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

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Physical & Chemical properties

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Reference
Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2021-05-03
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
comparable to guideline study with acceptable restrictions
Reason / purpose for cross-reference:
reference to same study
Qualifier:
no guideline followed
Principles of method if other than guideline:
Self-ignition properties of the test item were deduced from data of the Grewer oven test.
GLP compliance:
no
Specific details on test material used for the study:
CAS No.: 199387-97-8
Purity: 100 area%
Batch No.: LAM-2487-3
Expiry date: 2021-05-28
Key result
Remarks on result:
no self ignition observed under the test conditions

The temperature of the solid test item and the temperature of the reference substance (graphite) do not differ until approx. 160 °C. At this point a slightly endothermic peak was observed followed by a larger endothermic event. Around 260 °C a very low exothermic event was recorded. Additional heating until 359 °C did not lead to a difference in the temperature profile of the test item and the reference substance.

No self-ignition test was performed with the test item. However, self-ignition of a solid can be excluded, if in the course of the Grewer oven test there is no temperature excursion of the sample of more than 400 °C (in relation to the reference sample). Based on data from the Grewer oven test the maximum observed temperature of the test item was 359 °C (no difference to the reference sample), which is quite below 400 °C. Therefore, the test item does not have any self-ignition properties.

Conclusions:
The test item does not have any self-ignition properties.
Executive summary:

The temperature of the solid test item and the temperature of the reference substance (graphite) do not differ until approx. 160 °C. At this point a slightly endothermic peak was observed followed by a larger endothermic event. Around 260 °C a very low exothermic event was recorded. Additional heating until 359 °C did not lead to a difference in the temperature profile of the test item and the reference substance. It can therefore be concluded, that the test-item does not have any self-ignition properties. 


 


No self-ignition test was performed with the test item. However, self-ignition of a solid can be excluded, if in the course of the Grewer oven test there is no temperature excursion of the sample of more than 400 °C (in relation to the reference sample). Based on data from the Grewer oven test the maximum observed temperature of the test item was 359 °C (no difference to the reference sample), which is quite below 400 °C. Therefore, the test item does not have any self-ignition properties.

Description of key information

Based on results from the Grewer oven test, the test item does not have any self-ignition properties.

Key value for chemical safety assessment

Additional information