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Physical & Chemical properties

Boiling point

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Administrative data

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Reference
Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Between 29 July 1999 and 15 December 1999.
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to other study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
OECD Guideline 103 (Boiling Point)
Version / remarks:
Method 103 of the OECD Guidelines for Testing of Chemicals, 27 July 1995.
Deviations:
not specified
GLP compliance:
yes (incl. QA statement)
Type of method:
differential scanning calorimetry
Specific details on test material used for the study:
No futher details specified in the study report.
Key result
Boiling pt.:
> 673 K
Atm. press.:
100.02 kPa
Decomposition:
yes
Decomp. temp.:
476 K

Thermographic data - Determination 1

Thermal event

Interpretation

Temperature

°C

K

Onset of exotherm

(low energy)

Possible onset of decomposition

203.3

476

No endothermic behaviour occurred up to a temperature of 400 ± 0.5 °C (673 ± 0.5 K). The boiling temperature is therefore considered to be greater than 673 ± K.

Atmospheric pressure: 100.20 kPa

 

Thermographic data - Determination 2

Thermal event

Interpretation

Temperature

°C

K

Onset of exotherm

(low energy)

Possible onset of decomposition

203.3

476

No endothermic behaviour occurred up to a temperature of 400 ± 0.5 °C (673 ± 0.5 K). The boiling temperature is therefore considered to be greater than 673 ± K.

Atmospheric pressure: 100.20 kPa

Conclusions:
The boiling temperature of has been determined to be greater than 673 + 0.5 K at 100.02 kPa.
Low energy exothermic behaviour from approximately 476 K suggests that there is some chemical change (possible onset of decomposition) of the material during the determination.
Executive summary:

Greater than 673 + 0.5 K at 100.02 kPa, by differential scanning calorimetry, using ASTM E537-86 and Method 103 of the OECD Guidelines for Testing of Chemicals, 27 July 1995.

Low energy exothermic behaviour from approximately 476 K suggests that there was some chemical change (possible onset of decomposition) of the material during the determinations.

 

From vapour pressure data (Safepharm Laboratories Project Number 4451285) and the chemical structure, the boiling temperature is estimated to be greater than 673 K at 101.325 kPa.

Description of key information

Greater than 673 + 0.5 K at 100.02 kPa

Key value for chemical safety assessment

Boiling point at 101 325 Pa:
673 K

Additional information

Greater than 673 + 0.5 K at 100.02 kPa, by differential scanning calorimetry, using ASTM E537-86 and Method 103 of the OECD Guidelines for Testing of Chemicals, 27 July 1995.

Low energy exothermic behaviour from approximately 476 K suggests that there was some chemical change (possible onset of decomposition) of the material during the determinations.

 

From vapour pressure data (Safepharm Laboratories Project Number 4451285) and the chemical structure, the boiling temperature is estimated to be greater than 673 K at 101.325 kPa.