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Diss Factsheets
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EC number: 225-245-2 | CAS number: 4736-60-1
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
General:
Pay attention to self-protection. Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim warm, in a stabilized position and covered. Do not leave victims unattended. If the casualty is unconscious: Place the victim in the recovery position.
Description of first aid measures
Inhalation:
Inhalation is possible if aerosols, mists, dusts, or smoke form. Move victims into fresh air. With labored breathing: Provide with oxygen. Consult a doctor. If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin Contact:
Wash off affected area immediately with plenty of water for at least 15 minutes. With liposoluble substances, products, or preparations, continue decontamination with polyethylene glycol 400 after initial rinsing with water and then wash with water and soap. If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes. Consult an ophthalmologist immediately if the symptoms persist. When dealing with caustic substances, notify emergency physician immediately (key words: burns in eye).
Ingestion:
Rinse mouth. Immediately give large quantities of water to drink. Obtain medical attention. When dealing with caustic substances, notify emergency physician immediately.
Most important symptoms and effects, both acute and delayed:
Irritation of skin and mucous membranes Corrosive daze, Headache, vertigo, somnolence (sleepiness), nausea. Aspiration in the lungs might cause a chemical pneumonia. Aspiration may cause pulmonary oedema and pneumonitis. Health injuries may be delayed.
Indication of any immediate medical attention and special treatment needed
Hazards:
Strongly irritating to corrosive. Harmful by inhalation, in contact with skin and if swallowed. Vapours may cause drowsiness and dizziness.
Treatment:
In case of substances with high water solubility, inhalation of vapors, aerosols, mists, and smoke from caustic substances, products, and preparations, as well as caustic gases, results in irritations up to formation of necrosis in the upper respiratory tract. The initial focus is on the local action: signs of irritation of the respiratory tract such as coughing, burning behind the sternum, tears, burning in the eyes or nose. There is a fundamental risk of acute toxic pulmonary edema! In case of substances with low water solubility, only slight local irritations may appear at first, but after several hours of latency without symptoms, may develop into increasingly labored breathing and cyanosis as a result of a delayed pulmonary edema. There is a danger of underestimating the severity of the intoxication!
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
Water spray
jet foam
Carbon Dioxide
Dry powder
Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
Hazard-determining flue gases might develop in case of fire: Oxides of phosphorus Iodine vapours May be released in case of fire: hydrogen iodide.
Advice for firefighters
Special fire fighting procedures:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws. In case of fire, remove the endangered barrels and bring to a safe place, if this can be done safely. Keep out unprotected persons.
Special protective equipment for fire-fighters:
wear a self contained respiratory apparatus full protective suit
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Wear personal protective equipment; Avoid formation of dust. Ensure sufficient ventilation.
For non-emergency personnel:
No data available.
For emergency responders:
No data available.
Environmental Precautions:
Observe regulations on prevention of water pollution (check, dam up, cover up). Do not allow entrance in sewage water, soil, stretches of water, drainage systems, surface water. If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Collect up material. Transfer into suitable containers for recovery or disposal. Disposal according to local authority regulations. Avoid dust formation.
Handling and storage
Precautions for safe handling:
Provide sufficient ventilation and exhaust at the workplace. Avoid dust formation. Avoid residues of the product on the containers. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes, skin, and clothing. If there is the possibility of skin/eye contact, the indicated hand/eye/body protection should be used. The personal protective equipment used must meet the requirements of Regulation (EU) 2016/425 and amendments (CE certification). It should be defined in the work place in the form of a risk analysis according to Regulation (EU) 2016/425 and amendments.
Conditions for safe storage, including any incompatibilities:
Keep away from combustion sources such as sparks, flames and unprotected light sources When using do not smoke. Take precautionary measures against static charges, keep away from sources of ignition. In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations. Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions.
Storage Class: 6.1 B: Non-combustible substances of acute toxicity, categories 1 and 2 / very toxic substances
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3464
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3464
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Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3464
Shipping information
- Proper shipping name and description:
- ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. (Ethyl-triphenyl-phosphonium-iodide)
- Chemical name:
- Ethyl-triphenyl-phosphonium-iodide
- Labels:
- 6.1
- Marine pollutant
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3464
Shipping information
- Proper shipping name and description:
- Organophosphorus compound, solid, toxic, n.o.s. (Ethyl-triphenyl-phosphonium-iodide)
- Chemical name:
- Ethyl-triphenyl-phosphonium-iodide
- Labels:
- 6.1
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Additional transport information
Additional information
- Special provisions / remarks / other:
- Loading instructions/Remarks:
IATA_C: ERG-Code 6L
IATA_P: ERG-Code 6L
Keep separate from foodstuffs, luxury foods, feedstuffs.
Combination traffic:
Labelling of containers / shipping units following main product run as per sea or air transport regulations.
Exposure controls / personal protection
Exposure controls
Appropriate Engineering Controls:
Provide appropriate exhaust ventilation at machinery. Provide for installation of emergency shower and eye bath.
Individual protection measures, such as personal protective equipment
Eye/face protection:
Safety glasses with side-shields conforming to EN166 or When handling larger quantities: basket-shaped glasses
Hand Protection:
Material: Nitrile.
Glove thickness: 0.11 mm
Guideline: DIN EN 374
Additional Information: Applies to handling for brief periods or of small amounts
Material: Nitrile/Chloroprene
Glove thickness: 0.65 mm
Guideline: DIN EN 374
Additional Information: Applies to handling for longer periods or of large amounts
Additional Information: Selection of protective gloves to meet the requirements of specific workplaces., Suitability for specific workplaces should be clarified with protective glove manufacturers., The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials., Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined according to EN 374 due to the many different influential factors involved (e.g. temperature).
Skin and Body Protection:
Select materials and equipment for physical protection depending on the concentration and volume of hazardous substances and the workplace involved.
Respiratory Protection:
When handling for a short time: Respirator with P2 particle filter In the case of respirable dust, use self-contained breathing apparatus. Note time limit for wearing respiratory protective equipment.
Hygiene measures:
Prevent the formation of dust. Take off immediately all contaminated clothing. Provide adequate ventilation.
Environmental Controls:
No data available.
Stability and reactivity
Reactivity:
No data available.
Chemical Stability:
No data available.
Possibility of hazardous reactions:
No dangerous reaction known under conditions of normal use. No special precautions.
Conditions to avoid:
No decomposition if used as directed. Take precautionary measures against static discharges. Avoid shock and friction.
Incompatible Materials:
strong alkalis
Hazardous Decomposition Products:
No hazardous decomposition products known.
Disposal considerations
Waste treatment methods
General information:
No data available.
Disposal methods:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority. Disposal according to local authority regulations. Pack and label wastes like the pure substance. Do not detach label from the delivery containers prior to disposal.
Contaminated Packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.