Notified classification and labelling according to CLP criteria
General Section
EC / List no. Name CAS Number Additional Notified Information
202-966-0 4,4'-methylenediphenyl diisocyanate 101-68-8 State/Form

Classification Labelling Specific Concentration limits, M-Factors Notes Classification affected by Impurities / Additives
Hazard Class and Category Code(s) Hazard Statement Code(s) Hazard Statement Code(s) Supplementary Hazard Statement Code(s)
Skin Irrit. 2 H315 H315 Resp. Sens. 1; : C ≥ .1 %
Eye Irrit. 2; : C ≥ 5 %
Skin Irrit. 2; : C ≥ 5 %
STOT SE 3; : C ≥ 5 %
Note 2
Note C
 
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:mouth, ph...) H335
STOT SE 3 H335 (mouth, pharynx,...) H335

Signal Words Pictograms
Danger
GHS07
Exclamation mark
GHS08
Health hazard
Detailed Information on classification and labelling

Classification

 
Physical and Chemical hazards
  Hazard Category Hazard Statement Reason for no Classification
Explosives     data conclusive but not sufficient for classification
Flammable Gases and Chemically Unstable Gases     data lacking
Flammable Aerosols     data lacking
Oxidising Gases     data lacking
Gases Under Pressure     data lacking
Flammable Liquids     data conclusive but not sufficient for classification
Flammable Solids     data lacking
Self-reactive Substances and Mixtures     data conclusive but not sufficient for classification
Pyrophoric Liquids     data lacking
Pyrophoric Solids     data lacking
Self-heating Substances and Mixtures     data lacking
Substances and Mixtures which in contact with water emit flammable gases     data lacking
Oxidising Liquids     data conclusive but not sufficient for classification
Oxidising Solids     data lacking
Organic Peroxides     data lacking
Substances and Mixtures corrosive to Metals     data lacking
Desensitized Explosives     Data lacking
 
Human Health hazards
  Hazard Category Hazard Statement Reason for no Classification
Acute Toxicity - Oral     data conclusive but not sufficient for classification
Acute Toxicity - Dermal     data lacking
Acute Toxicity - Inhalation Acute Tox. 4 H332  
Skin Corrosion / Irritation Skin Irrit. 2 H315  
Serious Eye Damage / Eye Irritation Eye Irrit. 2 H319  
Respiratory Sensitisation Resp. Sens. 1 H334  
Skin Sensitisation Skin Sens. 1 H317  
Aspiration Hazard     data lacking
Germ Cell Mutagenicity Hazard Category Hazard Statement Reason for no Classification
Germ Cell Mutagenicity     data lacking
Carcinogenicity Hazard Category Hazard Statement Reason for no Classification
Carcinogenicity     data lacking
Reproductive Toxicity Hazard Category Hazard Statement Reason for no Classification
Reproductive Toxicity     data lacking
Effects on or via Lactation     data lacking
Specific target organ toxicity - Single Hazard Category Hazard Statement Reason for no Classification
Specific target organ toxicity - Single STOT SE 3 H335  
     Affected Organs other:mouth, pharynx, oesophagus and gastrointestinal tract
Specific target organ toxicity - Single STOT SE 3 H335  
     Affected Organs mouth, pharynx, oesophagus and gastrointestinal tract
Specific target organ toxicity - Repeated Hazard Category Hazard Statement Reason for no Classification
Specific target organ toxicity - Repeated     data lacking
 
Environmental Hazards
Hazardous to the aquatic environment Hazard Category Hazard Statement Reason for no Classification
Hazardous to the aquatic environment - acute     data lacking
Hazardous to the aquatic environment - chronic     data lacking
Hazardous to the atmospheric environment Hazard Category Hazard Statement Reason for no Classification
Hazardous to the ozone layer     data lacking

Additional Hazard Classes Additional Hazard Statements
No available Data

Labelling

Hazard Statement Code(s) Phrase Additional Text
H315 Causes skin irritation.  
H319 Causes serious eye irritation.  
H317 May cause an allergic skin reaction.  
H332 Harmful if inhaled.  
H335 May cause respiratory irritation.  
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.  

Note Title Note Text
Note 2 The concentration of isocyanate stated is the percentage by weight of the free monomer calculated with reference to the total weight of the mixture.
Note C Some organic substances may be marketed either in a specific isomeric form or as a mixture of several isomers. , In this case the supplier must state on the label whether the substance is a specific isomer or a mixture of isomers.