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EC number: 288-107-0 | CAS number: 85650-96-0
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Short-term toxicity to aquatic invertebrates
Administrative data
Link to relevant study record(s)
Description of key information
Pigment additive Kr 1789 Stck. Ber. 100% (CAS 85650-96-0): There is a high probability that the product is not acutely harmful to aquatic invertebrates.
Key value for chemical safety assessment
Additional information
The Pigment additive Kr 1789 Stck. Ber. 100% (CAS 85650-96-0) is composed of Copper phthalocyanine monosulfonic acid (CAS 28901-96-4) and oleylamine (CAS 112-90-3).
The key study on acute toxicity of the target item Pigment additive Kr 1789 to Daphnia magna has been conducted according to OECD 202 following a semi-static test system setup (BASF SE 2017). At test termination after 48 h an "Effective Loading Rate" > 100 mg/L (nominal) was determined. No effects were observed up to the highest loading rate.
For the constituents Copper phthalocyanine monosulfonic acid (CAS 28901-96-4) and oleylamine (CAS 112-90-3) supporting studies are available.
For the pigment compound Copper phthalocyanine monosulfonic acid (CAS 28901-96-4) the assessment is based on toxicity data on Daphnia magna, as well as on read-across data for the structural analogous substance copper phthalocyanine (CAS 147-14-8). Daphnids (Daphnia magna) were exposed in a GLP guideline study according to OECD 202 for 48 hours. The effect of CAS 59160-79-1 on the swimming behavior was investigated; 48-h EC50 value of > 100 mg/l (nominal) were determined (ibacon, 2015). Supporting this, the structural analogue CAS 147-14-8 was investigated in several studies regarding toxicity in aquatic invertebrates. One study comparable to OECD TG 202 revealed an EC50 > 500 mg/L (BASF AG 1989). BASF AG (2001) showed EC 50 > 100 mg/L in a screening study according EED Directive 93/32/EWG. Finally, a screening test according to EEC Directive 93/32/EEC confirmed these findings with an EC50 > 100 mg/L (nominal; BASF AG 2004).
In summary, Copper phthalocyanine (CAS 147-14-8) is concluded to be with high probability not harmful to aquatic invertebrates.
Further supporting study on the toxicity of oleylamine (CAS 112 -90 -3) to aquatic invertebrates was assessed in a study according to OECD TG 202 under static conditions. Daphnia magna was used as test species. The test concentrations were analytically verified. A 48 -h EC50 was determined to be 0.011 mg/L (nominal; Mark et al., 1995).
It can be concluded that oleylamine is acutely very toxic to aquatic invertebrates.
In conclusion Pigment additive Kr 1789 is not acutely harmful for aquatic invertebrates.
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