Registration Dossier
Registration Dossier
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EC number: 413-110-2 | CAS number: 135861-56-2
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures:
General notes: In all cases of doubt, or if you feel unwell, get medical attention.
Following inhalation: If inhaled, remove to fresh air if you feel unwell. Get medical aid if cough or other symptoms appear.
Following skin contact: In case of contact, immediately flush skin with plenty of water and soap. Remove contaminated clothing and shoes. Get medical aid if symptoms occur. Wash clothing and shoes before reuse.
Following eye contact: In case of contact, immediately flush eyes with water or normal saline for at least 15 minutes, occasionally lifting the upper a ndlower eyelids. Check for and remove any contact lenses if easily possible. Get medical aid if symptoms occur.
Following ingestion: If swallowed, induce vomiting under the guidance of professional doctors. If the injured is fully conscious: wash mouth out wi th water. Never give anything by mouth to an unconscious person. Get medical aid.
Most important symptoms and effects, both acute and delayed: See "Toxicological information" for more information.
Indication of any immediate medical attention and special treatment needed: Treat symptomatically and supportively.
General notes: In all cases of doubt, or if you feel unwell, get medical attention.
Following inhalation: If inhaled, remove to fresh air if you feel unwell. Get medical aid if cough or other symptoms appear.
Following skin contact: In case of contact, immediately flush skin with plenty of water and soap. Remove contaminated clothing and shoes. Get medical aid if symptoms occur. Wash clothing and shoes before reuse.
Following eye contact: In case of contact, immediately flush eyes with water or normal saline for at least 15 minutes, occasionally lifting the upper a ndlower eyelids. Check for and remove any contact lenses if easily possible. Get medical aid if symptoms occur.
Following ingestion: If swallowed, induce vomiting under the guidance of professional doctors. If the injured is fully conscious: wash mouth out wi th water. Never give anything by mouth to an unconscious person. Get medical aid.
Most important symptoms and effects, both acute and delayed: See "Toxicological information" for more information.
Indication of any immediate medical attention and special treatment needed: Treat symptomatically and supportively.
Fire-fighting measures
Extinguishing media:
Suitable extinguishing media: Water spray, foam, sand, dry chemical powder, CO2.
Unsuitable extinguishing media: N/A
Special hazards arising from the substance or mixture:
Finely dispersed particles may form combustible/ explosive mixtures in air.
Hazardous combustion products: In case of a fire, oxides of carbon, hydrocarbons, fume and smoke may be generated.
Advice for firefighters: Water spray can be use to keep fire-exposed containers cool. As in any fire, wear a self-contained breathing apparatus in pressure-demand, and full protective gear. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Move containers from fire area if this can be done without risk. Avoid breathing dust/fume. Prevent run off from fire control dilution from entering streams or drinking water supply.
Suitable extinguishing media: Water spray, foam, sand, dry chemical powder, CO2.
Unsuitable extinguishing media: N/A
Special hazards arising from the substance or mixture:
Finely dispersed particles may form combustible/ explosive mixtures in air.
Hazardous combustion products: In case of a fire, oxides of carbon, hydrocarbons, fume and smoke may be generated.
Advice for firefighters: Water spray can be use to keep fire-exposed containers cool. As in any fire, wear a self-contained breathing apparatus in pressure-demand, and full protective gear. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Move containers from fire area if this can be done without risk. Avoid breathing dust/fume. Prevent run off from fire control dilution from entering streams or drinking water supply.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
For non-emergency personnel:
Protective equipment: Use proper personal protective equipment as indicated in "Exposure controls/personal protection".
Emergency procedures: Evacuate and ventilate spill area. Remove all sources of ignition or heat. Use spark-proof tools and dust explosion-proof equipment. Do not walk through spilled material. Avoid breathing dust/vapor/fume. Review "fire-fighting measures" and "handling and storage" sections before proceeding with clean-up.
For emergency responders: N/A
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Methods and material for containment and cleaning up:
For containment: Stop leak if safe to do so. Move containers from spill area. Avoid generating dusty conditions.
For cleaning up: Sweep up or scoop up material carefully, and then place into a suitable disposal container for disposal according to local regulatio ns.
Other information: Contaminated floor may be flushed with water to chemical sewer.
Reference to other sections: Use proper personal protective equipment as indicated in Section 8. And see "Disposal considerations" for disposal information.
For non-emergency personnel:
Protective equipment: Use proper personal protective equipment as indicated in "Exposure controls/personal protection".
Emergency procedures: Evacuate and ventilate spill area. Remove all sources of ignition or heat. Use spark-proof tools and dust explosion-proof equipment. Do not walk through spilled material. Avoid breathing dust/vapor/fume. Review "fire-fighting measures" and "handling and storage" sections before proceeding with clean-up.
For emergency responders: N/A
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Methods and material for containment and cleaning up:
For containment: Stop leak if safe to do so. Move containers from spill area. Avoid generating dusty conditions.
For cleaning up: Sweep up or scoop up material carefully, and then place into a suitable disposal container for disposal according to local regulatio ns.
Other information: Contaminated floor may be flushed with water to chemical sewer.
Reference to other sections: Use proper personal protective equipment as indicated in Section 8. And see "Disposal considerations" for disposal information.
Handling and storage
Precautions for safe handling:
Protective measures: Training should be provided to anyone working with or near this material. Training should cover potential health effects and
proper handling techniques. Avoid contact with eyes, skin and clothing. Avoid ingestion and inhalation. Remove contaminated clothing and shoes. Wash clothing and shoes thoroughly before reuse.
Measures to prevent fire: Ensure good local exhaust ventilation. Handle and open container with care. Keep container tightly closed and away fromincompatible substances (see "stability and reactivity"), any sources of ignition or heat (e.g. open flames, hot surfaces). Take precautionary measures against electrostatic discharges. Minimize dust generation and accumulation. Empty containers retain product residue. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. The work area should b equipped with the corresponding speciesnd quantity of fire equipment and leakage emergency equipment.
Measures to prevent aerosol and dust generation: Ensure good local exhaust ventilation. Handle and open container with care. Minimize dust gener at ion and accumulation.
Measures to protect the environment: Do not allow this product to be released to the environment without proper treatment.
Advice on general occupational hygiene: This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and pro cessed. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Conditions for safe storage, including any incompatibilities: Do not enter storage areas and confined spaces unless adequately ventilated. Containe rs that have been opened must be carefully resealed and kept upright to prevent leakage. Keep container tightly closed when not in use. Store in a c ool, dry, well-ventilated area away from incompatible substances (see "stability and reactivity"), any sources of ignition or heat (e.g. open flames, hot surfaces), f ood, drink and feedstuffs. Inspect regularly for deficiencies such as damage or leaks. Treat carefully, avoid physical damage to containers. The stor age area should be equipped with the corresponding species and quantity of fire equipment and leakage emergency equipment.
Specific end use(s):
Recommendations: Polypropylene.
Industrial sector specific solutions: N/A
Protective measures: Training should be provided to anyone working with or near this material. Training should cover potential health effects and
proper handling techniques. Avoid contact with eyes, skin and clothing. Avoid ingestion and inhalation. Remove contaminated clothing and shoes. Wash clothing and shoes thoroughly before reuse.
Measures to prevent fire: Ensure good local exhaust ventilation. Handle and open container with care. Keep container tightly closed and away fromincompatible substances (see "stability and reactivity"), any sources of ignition or heat (e.g. open flames, hot surfaces). Take precautionary measures against electrostatic discharges. Minimize dust generation and accumulation. Empty containers retain product residue. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. The work area should b equipped with the corresponding speciesnd quantity of fire equipment and leakage emergency equipment.
Measures to prevent aerosol and dust generation: Ensure good local exhaust ventilation. Handle and open container with care. Minimize dust gener at ion and accumulation.
Measures to protect the environment: Do not allow this product to be released to the environment without proper treatment.
Advice on general occupational hygiene: This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and pro cessed. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Conditions for safe storage, including any incompatibilities: Do not enter storage areas and confined spaces unless adequately ventilated. Containe rs that have been opened must be carefully resealed and kept upright to prevent leakage. Keep container tightly closed when not in use. Store in a c ool, dry, well-ventilated area away from incompatible substances (see "stability and reactivity"), any sources of ignition or heat (e.g. open flames, hot surfaces), f ood, drink and feedstuffs. Inspect regularly for deficiencies such as damage or leaks. Treat carefully, avoid physical damage to containers. The stor age area should be equipped with the corresponding species and quantity of fire equipment and leakage emergency equipment.
Specific end use(s):
Recommendations: Polypropylene.
Industrial sector specific solutions: N/A
Transport information
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Marine transport (UN RTDG/IMDG)
- UN number:
- N/A
Shipping information
- Proper shipping name and description:
- N/A
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Exposure controls / personal protection
Exposure Limit: There are no specific exposure limits established for this substance. It is recommended that the following exposure limits for "Particulates, not otherwise regulated (PNOR)" be used.
Composition: CAS# 135861-56-2
TLV-TWA 10 mg/m3 (ACGIH, total dust, particulate matter containing < 1% crystalline silica)
TLV-TWA 3 mg/m3(ACGIH, respirable fraction, particulate matter containing no asbestos and <1% crystalline silica)
PEL-TWA 15 mg/m3 (OSHA, total particulate, as the Particulates Not Otherwise Regulated (PNOR))
PEL-TWA 5 mg/m3 (OSHA, respirable fraction, as the Particulates Not Otherwise Regulated (PNOR))
Information on monitoring procedures: No information found.
Exposure controls:
Appropriate engineering controls: Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Personal protection equipment:
Eye and face protection: Dust service goggles should be worn to prevent mechanical injury or other irritation to eyes due to airborne particles which may result from handling product.
Skin protection:
Hand protection: Wear appropriate protective gloves to prevent skin exposure.
Other skin protection: Wear appropriate protective clothing to prevent skin exposure.
Respiratory protection: An appropriate respirator or mask should be used whenever workplace conditions warrant a respirator's use. A full face positive pressure supplied-air respirator or a self contained breathing apparatus should be used when large spilled or fire.
Other protection: To maintain good health habits. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash hands thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Environmental exposure controls: Do not allow this product to be released to the environment without proper treatment.
Composition: CAS# 135861-56-2
TLV-TWA 10 mg/m3 (ACGIH, total dust, particulate matter containing < 1% crystalline silica)
TLV-TWA 3 mg/m3(ACGIH, respirable fraction, particulate matter containing no asbestos and <1% crystalline silica)
PEL-TWA 15 mg/m3 (OSHA, total particulate, as the Particulates Not Otherwise Regulated (PNOR))
PEL-TWA 5 mg/m3 (OSHA, respirable fraction, as the Particulates Not Otherwise Regulated (PNOR))
Information on monitoring procedures: No information found.
Exposure controls:
Appropriate engineering controls: Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Personal protection equipment:
Eye and face protection: Dust service goggles should be worn to prevent mechanical injury or other irritation to eyes due to airborne particles which may result from handling product.
Skin protection:
Hand protection: Wear appropriate protective gloves to prevent skin exposure.
Other skin protection: Wear appropriate protective clothing to prevent skin exposure.
Respiratory protection: An appropriate respirator or mask should be used whenever workplace conditions warrant a respirator's use. A full face positive pressure supplied-air respirator or a self contained breathing apparatus should be used when large spilled or fire.
Other protection: To maintain good health habits. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash hands thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Environmental exposure controls: Do not allow this product to be released to the environment without proper treatment.
Stability and reactivity
Reactivity: Has not been reported.
Chemical stability: Stable under normal storage and handling conditions.
Possibility of hazardous reactions: Has not been reported.
Conditions to avoid: Incompatible materials, dust generation, sources of ignition or heat (e.g. open flames, hot surfaces).
Incompatible materials: Strong oxidizing agents.
Hazardous decomposition products: Decomposition will not occur if handled and stored properly. In case of a fire, oxides of carbon, hydrocarbons, fume and smoke may be generated.
Chemical stability: Stable under normal storage and handling conditions.
Possibility of hazardous reactions: Has not been reported.
Conditions to avoid: Incompatible materials, dust generation, sources of ignition or heat (e.g. open flames, hot surfaces).
Incompatible materials: Strong oxidizing agents.
Hazardous decomposition products: Decomposition will not occur if handled and stored properly. In case of a fire, oxides of carbon, hydrocarbons, fume and smoke may be generated.
Disposal considerations
Waste treatment methods:
Chemical waste generators must determine whether a discardedchemical is classified as a hazardous waste. Disposal should be inaccordance with applicable regional, national and local laws andregulations.
The generation of waste should be avoided or minimized whereverpossible. Contaminated packaging material should be treated equivalent toresidual chemical. Clean packaging material should be subjected to wastemanagement schemes (recovery recycling, reuse) according to locallegislation. Avoid dispersal of spilled material and runoff and contact withsoil, waterways, drains andsewers.
Refer to "Handling and Storage" and "ExposureControls/Personal Protection" for additional handling information andprotection of employees.
Chemical waste generators must determine whether a discardedchemical is classified as a hazardous waste. Disposal should be inaccordance with applicable regional, national and local laws andregulations.
The generation of waste should be avoided or minimized whereverpossible. Contaminated packaging material should be treated equivalent toresidual chemical. Clean packaging material should be subjected to wastemanagement schemes (recovery recycling, reuse) according to locallegislation. Avoid dispersal of spilled material and runoff and contact withsoil, waterways, drains andsewers.
Refer to "Handling and Storage" and "ExposureControls/Personal Protection" for additional handling information andprotection of employees.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
