Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Additional information on environmental fate and behaviour

Currently viewing:

Administrative data

Endpoint:
additional information on environmental fate and behaviour
Type of information:
experimental study
Adequacy of study:
weight of evidence
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
other: Original data are not available.

Data source

Reference
Reference Type:
publication
Title:
Estimation of the Half-Life of Sodium Hydroxide Aerosol in the Atmosphere.
Author:
US EPA
Year:
1988
Bibliographic source:
Memorandum from Dave Guinnup and Richard Scheffe to Timothy Mohin. Office of Air Quality Planning and Standards, Research Triangle Park, North Carolina. May 5, 1988

Materials and methods

Principles of method if other than guideline:
No data
GLP compliance:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
Sodium hydroxide
EC Number:
215-185-5
EC Name:
Sodium hydroxide
Cas Number:
1310-73-2
Molecular formula:
HNaO
IUPAC Name:
sodium hydroxide

Results and discussion

Any other information on results incl. tables

Sodium hydroxide is very short lived in the atmosphere. Sodium hydroxide released to the atmosphere as an aerosol in solution with water will be neutralized as a result of its reaction with carbon dioxide (US EPA, 1989)*. The principal reaction products are sodium carbonate and water. The atmospheric half life of sodium hydroxide has been estimated at 13 seconds. Based on model calculations, this degradation results in only 0.4% of the NaOH emitted to air remaining in the air at a point 200 metres from the emission point.

*: US EPA (1989): Assessment of sodium hydroxide as a potentially toxic air pollutant. Federal Register, 54, No.9, January 1989. United States Environmental Protection Agency, United States.

Applicant's summary and conclusion

Conclusions:
As the hydroxyl ion is the neutralized species, the same reaction will occur with the hydroxyl ion of potassium hydroxide. The formed carbonate salts will be washed out by rain.