Phenol, paraalkylation products with C12-rich branched olefins derived from propene oligomerisation, ethane-1,2-diol, carbonate, sulfurized, calcium salts, overbased, reacted with alkylene carbonate, including distillates (petroleum), heavy paraffinic C10-C50

Boiling point

Link to relevant study record(s)

Reference

Endpoint:

boiling point

Type of information:

experimental study

Adequacy of study:

key study

Study period:

Feb-May 2013

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

other: A modern study conducted in compliance with GLP standards and followed OECD Guidelines

Qualifier:

according to guideline

Guideline:

OECD Guideline 103 (Boiling point/boiling range)

Deviations:

no

GLP compliance:

yes

Type of method:

method according to Siwoloboff

Specific details on test material used for the study:

Identifier: EXP1200078
Appearance: Very dark brown (almost black) viscous liquid
Batch: E00275-350
Sample Expiration Date: end-2013
Purity:100%

Key result

Boiling pt.:

> 178.3 - <= 400 °C

Atm. press.:

ca. 760 mm Hg

Decomposition:

ambiguous

Remarks:

Color change observed

Decomp. temp.:

ca. 300 °C

Remarks on result:

other: Boiling point not achieved; limitation of test instrumentation upper bound.

Determination of Melting Points for the Reference Standards

 

Reference Standard	Instrument Gradient (°C/min.)	Date Verification Performed	Recorded Melting Point (°C)	Average	Expected Melting Point/Range (°C)
Caffeine	1.0	2/26/13	237.0	--	237
Anthraquinone	1.0	2/26/13   2/27/13	285.3   285.1	285.2	284-286
Benzophenone	1.0	2/26/13   2/27/13	49.5   49.3	49.4	49-51
Note: All calculations were performed using Microsoft^®Excel 2000 in full precision mode. -------------------------------------------------------------------------------------------------------------- Determination of Boiling Point/Range for the Test Substance     Subsample ID Instrument Gradient (°C/min) Barometric Pressure (mm Hg) Start of Boiling Range  °C (K)^1 End of Boiling Range °C (K)^1 Boiling Point °C (K)^1   523C-189-BP-1   523C-189- BP-2   523C-189- BP-3     1.0   1.0   1.0     748   748   750     178.3 (451.5) 181.0 (454.2) 184.1 (457.3)     None Observed None Observed None Observed     None Observed None Observed None Observed   Overall Means: Standard Deviations: CV (%): 749 1 0.1 181.1 (454.3) 2.9 (2.9) 1.60 (0.64) n/a n/a n/a n/a n/a n/a ^1K (Kelvin) = °C + 273.15   Note: All calculations were performed using Microsoft^®Excel 2000 in full precision mode. Additionally, “n/a” denotes “not applicable”.

Conclusions:

The boiling point was determined using a modification of the Siwoloboff procedure which employed a Büchi Melting Point B-540 instrument with boiling point tubes and boiling point capillaries, also supplied by Büchi.

EXP1200078 thermally degraded as the instrument block temperature approached 350°C. No boiling point / range could be determined.

Executive summary:

The test substance thermally degraded as the instrument block temperature approached 350°C. No boiling point / range could be determined.

Description of key information

A Key GLP study conducted in accordance with OECD guideline.

The test substance thermally degraded as the instrument block temperature approached 350°C. No boiling point / range could be determined.

Additional information

Boiling point > 178.3 which was the temperature at which capillary bubbling was first observed. The sample degraded with further temperature increase.