Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 200-372-6 | CAS number: 58-27-5
Guidance on Safe Use
Administrative data
First-aid measures
General information:
Consult a physician. Show the safety data sheet to the doctor in attendance.
Inhalation:
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
Skin contact:
Wash off with soap and plenty of water.Consult a physician.
Eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Ingestion:
Never give anything by mouth to an unconscious person.Rinse mouth with water.Consult a physician.
Fire-fighting measures
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture:
Very high dust explosion hazard.
In case of fire, product may form irritant menadione vapors and toxic fumes such as CO.
Advice for firefighters:
Wear self contained breathing apparatus for fire fighting if necessary. Precipitate gases/vapours/mists with water spray.
Accidental release measures
Personal precautions,protective equipment and emergency procedures:
Use personal protective equipment according to the circumstances.
Collect spilled solid material avoiding dust formation.
Avoid breathing vapors, mist or gas.
Ensure adequate ventilation.
Evacuate personnel to safe areas.
Avoid breathing dust.
Environmental precautions:
Do not let product enter drains.
Methods and materials for containment and cleaning up:
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal in compliance with law.
Handling and storage
Precautions for safe handling:
When handling apply local exhaust ventilation.
Avoid formation of dust and aerosols; very high dust explosion hazard.
Take precautionary measures against electrostatic charging.
Wear protective equipment.
Avoid contact with eyes and skin.
Wash thoroughly with cold water after handling.
Conditions for safe storage:
Keep containers tightly closed and away from heat. Store in cool, dry and well ventilated place.
Avoid heat and light exposure, store separate from basic substances.
Standard packaging: carton boxes with inner polyethylene bag.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not regulated
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3077
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance,
solid, n.o.s (Menadione) - Chemical name:
- Menadione
- Labels:
- 9
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance,
solid, n.o.s (Menadione) - Chemical name:
- Menadione
- Labels:
- 9
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Appropriate engineering controls:
Install local dust collection device and overall ventilation device in the workplace, minimize the exposure opportunities to contact the product as far as possible.
Control parameters:
Components with workplace control parameters.
Average allowed concentration in eight-hour working day / Maximum allowed concentration in short exposure: No data available
Biological indicators: No data available
Personal protective equipment and measurement:
Respiratory protection: particulate dust respirator.
Hand protection: industrial quality gloves (PVC, rubber).
Eye protection: safety goggles with side-shields, face shield and eye-cleaning equipment.
Body protection: Complete suit protecting against chemicals and preventing penetration.
Hygiene measures: avoid the bare parts of the body to contact the product, don’t wear contaminated clothing, banded to eat, drink and smoke at workplace after working.
Environmental exposure controls:
No data available
Stability and reactivity
Conditions to avoid:
The product is stable under the suggested handling and storage conditions not causing dangerous reactions.
Materials to avoid:
Strong oxidising agents, strong acids, strong alkalis and iron container.
Hazardous decomposition products:
Irritant menadione vapours and fumes containing CO, CO2, are produced respectively by thermal decomposition or when the product burns.
Disposal considerations
Disposal methods of the substance/preparation:
Whatever cannot be saved for recovery or recycling should be managed in an appropriate waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations.
Disposal methods of the contaminated packaging:
Dispose of contaminated packaging and unused materials in accordance with federal, state and local requirements.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
