Reaction mass of perfluoro(dimethyl - N - Butylamine ) and perfluoro (methyl - di - N - propylamine) and perfluoro (dimethyl - N - propylamine and 2,2,3,3,5,5,6,6, octafluoro-4-(trifluoromethyl)morpholine and perfluoro-N-pentane

Flammability

Administrative data

Endpoint:

flammable solids

Data waiving:

study scientifically not necessary / other information available

Justification for data waiving:

other:

Cross-reference

Cross-reference 1

Reason / purpose for cross-reference:

data waiving: supporting information

Reference

Endpoint:

flash point of flammable liquids

Type of information:

experimental study

Adequacy of study:

key study

Study period:

6 - 19 Dec 2017

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Qualifier:

according to guideline

Guideline:

other: ASTM D7094. Standard Test Method for Flash Point by Modified Continuously Closed Cup (MCCCFP) Tester

Deviations:

no

GLP compliance:

yes

Type of method:

closed cup

Flash point apparatus:

other: Eraflash flash-point tester

Specific details on test material used for the study:

SOURCE OF TEST MATERIAL
- Source and lot/batch No.of test material: 002602456
- Physical state: colorless, clear liquid
- Expiration date of the lot/batch: 07 June 2020

STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: at room temperature
- Stability under test conditions: test substance stable in water, but extremely volatile

Key result

Remarks on result:

other: no flash point up to 61 °C (test item boiled)

No flash-point was observed below 61 °C, the temperature at which the test item boiled.

Interpretation of results:

GHS criteria not met

Conclusions:

MTDID 22327 has no flash point up to 61 °C according to ASTM D7094.

Executive summary:

The flash point of MTDID 22327 was tested using a closed-cup method. Starting at 25 °C, an attempt was made to ignite the vapour of the test substance for every 2 °C temperature rise. No flash was observed below 61 °C, at which temperature the test item boiled. The study was conducted in accordance with ASTM D7094 and was GLP compliant; therefore the study is considered reliable without restrictions.

Cross-reference 2

Reason / purpose for cross-reference:

data waiving: supporting information

Reference

Endpoint:

auto-ignition temperature (liquids)

Type of information:

experimental study

Adequacy of study:

key study

Study period:

6 - 19 Dec 2017

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Qualifier:

according to guideline

Guideline:

EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))

Deviations:

no

Qualifier:

according to guideline

Guideline:

DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)

Deviations:

no

GLP compliance:

yes

Specific details on test material used for the study:

SOURCE OF TEST MATERIAL
- Source and lot/batch No.of test material: 002602456
- Physical state: colorless, clear liquid
- Expiration date of the lot/batch: 07 June 2020

STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: at room temperature
- Stability under test conditions: test substance stable in water, but extremely volatile

Key result

Auto-ignition temperature:

> 650 °C

Atm. press.:

>= 1 022 - <= 1 033 hPa

Conclusions:

No auto-ignition of MTDID 22327 was registered up to 650 °C according to EU Method A.15.

Executive summary:

In a test of MTDID 22327, no auto-ignition was observed up to 650 °C. The study was conducted in accordance with EU Method A.15 and was GLP compliant; therefore the study is considered reliable without restrictions.