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Diss Factsheets

Administrative data

Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
10 JUL 2009 to 09 SEP 2009
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Guideline study (OECD 104)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2009
Report date:
2009

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
GLP compliance:
yes (incl. QA statement)
Type of method:
effusion method: vapour pressure balance

Test material

Constituent 1
Reference substance name:
Reaction mass of Fatty acids, montan-wax and Fatty acids, montan-wax, ethylene esters and Montan wax
EC Number:
914-475-5
Molecular formula:
R-CH2-COOR1OOC-CH2-R mainly
IUPAC Name:
Reaction mass of Fatty acids, montan-wax and Fatty acids, montan-wax, ethylene esters and Montan wax
Details on test material:
- Name of test material (as cited in study report): Licowax E
- Physical state: Solid (yellowish powder)
- Analytical purity: 99.6% (w/w)
- Storage condition of test material: Room temperature

Results and discussion

Vapour pressure
Temp.:
25 °C
Vapour pressure:
0 Pa

Any other information on results incl. tables

The vapour pressure was measured in the temperature range of 19 °C to 130 °C. Above 71 °C a vapour pressure could be measured. The measured vapour pressures at the corresponding temperatures are listed in the following table:

Temperature / °C

Vapour pressure / hPa

70.6

2.5 x 10-5

71.8

2.8 x 10-5

80.9

6.6 x 10-5

88.1

6.1 x 10-5

91.0

1.1 x 10-4

96.3

1.5 x 10-4

101.6

2.3 x 10-4

109.6

4.1 x10-4

116.4

6.4 x 10-4

123.5

8.5 x 10-4

130.1

1.2 x 10-3

A curve is shown that gives the vapour pressure (Iogarithmic scale) as a function of the inverse temperature (1/T, T in Kelvin). For better readability the temperature is reported in a centigrade scale. The values for 20, 25 and 50 °C are calculated, using the Antoine constants A, B and C.

T/°C

p/hPa

log (p/hPa) = A + B/(C+T[°C])

20

2,54E-07

A = 6,93571

25

4,28E-07

B = -3966,60

50

4,58E-06

C = 273,15

 Final Results

Vapour Pressure

The calculated vapour pressure values are extrapolated:

T / °C

p/hPa

p / Pa

20

2.5 x  10-7

2.5 x 10-5

25

4.3 x 10-7

4.3 x 10-5

50

4.6 x 10-6

4.6 x 10-4


Applicant's summary and conclusion

Conclusions:
The vapour pressure of the test substance is 0.000043 Pa at 25 °C.
Executive summary:

The vapour pressure of the test substance was determined in a guideline study (OECD TG 104). The vapour pressure is 0.000043 Pa at 25 °C.